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聚丙烯/有机改性蒙脱土纳米复合材料的制备及力学性能研究
引用本文:陈奎,杨瑞成,张天云,成生伟,马建忠.聚丙烯/有机改性蒙脱土纳米复合材料的制备及力学性能研究[J].兰州理工大学学报,2006,32(6):24-27.
作者姓名:陈奎  杨瑞成  张天云  成生伟  马建忠
作者单位:1. 兰州理工大学,材料科学与工程学院,甘肃,兰州,730050;中国科学院兰州化学物理研究所固体润滑国家重点实验室,甘肃,兰州,730000
2. 兰州师范高等专科学校,甘肃,兰州,730070
3. 兰州理工大学,材料科学与工程学院,甘肃,兰州,730050
基金项目:甘肃省自然科学基金(ZSO21-A25-028-C)
摘    要:针对两种有机蒙脱土(TJ-2型和KH-V6型),采用熔体插层法在双螺杆挤出机中制备出PP/OMMT纳米复合材料,并运用XRD和FTIR对所制得的复合材料进行表征.研究结果表明,两种OMMT片层都在PP基体中达到纳米级的分散.力学性能研究表明,相对PP而言,两种PP/OMMT纳米复合材料的硬度分别提高了11%和19%,抗冲击性能分别提高了18%和20%,且随着蒙脱土添加量的增加,冲击性能的变化符合逾渗脆韧转变机制.

关 键 词:聚丙烯  蒙脱土  纳米复合材料  逾渗
文章编号:1673-5196(2006)06-0024-04
收稿时间:2005-11-01
修稿时间:2005年11月1日

Preparation of polypropylene/OMMT nanocomposites and investigation of their mechanical properties
CHEN Kui,YANG Rui-cheng,ZHANG Tian-yun,CHENG Sheng-wei,MA Jian-zhong.Preparation of polypropylene/OMMT nanocomposites and investigation of their mechanical properties[J].Journal of Lanzhou University of Technology,2006,32(6):24-27.
Authors:CHEN Kui  YANG Rui-cheng  ZHANG Tian-yun  CHENG Sheng-wei  MA Jian-zhong
Institution:1. College of Materials Science and Engineering, Lanzhou Univ. of Tech. , Lanzhou 730050, China; 2. State Key Lab. of Solid Lubrication, Lanzhou Institute of Chemical Physics, chinese Academy of Sciences, Lanzhou 730000, China; 3. Lanzhou Normal College, Lanzhou 730070, China
Abstract:Aimed at two kinds of organically-modified montmorillonite,namely TJ-2 type(OMMT1) and KH-V6 type(OMMT2),the PP/OMMT nanocomposites were synthesized by means of melt intercalation in twin-screw extruder.The prepared composites were characterized with XRD and FTIR.It was shown by the investigation result that the dispersion of both OMMT1 and OMMT2 layers had reached nano-level in PP matrix.Relative to PP,mechanical property investigation showed that the addition of nano-particles could improve the hardness(up to 11% and 19%) and their notch impact strength(up to 18% and 20%);where the change of notch impact strength conformed to brittle-ductile mechanism of percolation.
Keywords:polypropylene  montmorillonite  nanocomposites  percolation
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