| 镧(Ⅲ)、铈(Ⅲ)与二元胺邻香草醛Schiff碱配合物的合成及其表征 |
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| 引用本文： | 娄兆文,王明雄.镧(Ⅲ)、铈(Ⅲ)与二元胺邻香草醛Schiff碱配合物的合成及其表征[J].湖北大学学报(自然科学版),1991(2). |
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| 作者姓名： | 娄兆文 王明雄 |
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| 作者单位： | 湖北大学化学系
(娄兆文)，湖北大学化学系(王明雄) |
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| 摘 要： | 本文报道了镧(Ⅲ)、铈(Ⅲ)与N,N’—亚乙基二(2—羟基—3—甲氧基苯甲亚胺)和N,N’,—邻亚苯基二(2—羟基—3—甲氧基苯甲亚胺)反应形成的固态配合物,通过元素分析、摩尔电导、红外光谱、电子光谱和热谱等研究了配合物的组成和性质。这些新配合物的组成可表示为:LaL(H_2O)_2]NO_3和Ce_2L·nH_2O(L=MSEA或MSPA,n=0或4)。
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| 关 键 词： | 镧 铈 Schiff配合物 合成 |
SYNTHESIS AND CHARACTERIZATION OF COMPLEXES OF La(III) ,Ce(III)WITH O-VA-NILLIN AND DIAMINE SCHIFF BASES |
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| Lou Zhaowen Wang Mingxiong.SYNTHESIS AND CHARACTERIZATION OF COMPLEXES OF La(III) ,Ce(III)WITH O-VA-NILLIN AND DIAMINE SCHIFF BASES[J].Journal of Hubei University(Natural Science Edition),1991(2). |
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| Authors: | Lou Zhaowen Wang Mingxiong |
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| Institution: | Department of Chemistry |
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| Abstract: | The new complexes of Lanthanum (III) and Cerium(III) with N,N' -Ethylenebis(3 -Methoxysalicylidenemine) (H2MSEA)or N, N' - o - Phenylenebis(3 - Methoxysalicylideneimine) (H2MSPA) have been prepared. The complexes have been characterized by Elementary Analysis,Conductivity , Infrared Spectra, Electronic Spectra and Differential Thermal Analysis. The results indicate that their compositions are LaL(H2O)2NO3and Ce2L3 nH2O (L=MSEA or MSPA,n = 0,4) , respectively. |
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| Keywords: | Lanthanum( III ) Cerium (III ) Diamine Schiff Bases Synthesis |
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