| 剪刀型双锌卟啉的合成、表征及组装性能 |
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| 引用本文： | 周再春,刘秋华. 剪刀型双锌卟啉的合成、表征及组装性能[J]. 湖南科技大学学报(自然科学版), 2008, 23(4) |
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| 作者姓名： | 周再春 刘秋华 |
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| 作者单位： | 湖南科技大学化学化工学院,湖南,湘潭,411201 |
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| 基金项目： | 国家自然科学基金项目 ， 湖南科技大学博士启动基金项目 |
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| 摘 要： | 利用"bottom-up"合成策略设计和构筑了一个剪刀型锌双卟啉1,即先合成它的两类构件化合物:1,8-二[3-(氯羰基)苄氧基]蒽醌6和5-(3-氨基苯基)-10,15,20-三苯基卟啉7,然后通过酰氯和氨基的缩合得到目标化合物.详细报导了化合物1、4、5、8、9的合成和表征,并讨论了目标化合物1的结构特点和与双功能客体(Bpy)的组装性能.
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| 关 键 词： | 双卟啉 " bottom-up" 方法 分子组装 分子器件 |
Synthesis, Characterization and Assembly Properties of Tweezers-type Bis (zinc porphyrin) |
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| ZHOU Zai-chun,LIU Qiu-hua. Synthesis, Characterization and Assembly Properties of Tweezers-type Bis (zinc porphyrin)[J]. Journal of Hunan University of Science & Technology(Natural Science Editon), 2008, 23(4) |
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| Authors: | ZHOU Zai-chun LIU Qiu-hua |
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| Abstract: | A tweezers-type bis ( zinc porphyrin) 1 was designed and constructured according to the " bottom-up" method. That is, its two building block: 1,8-bis [3-(chlorocarbonyl)benzyloxy]anthraquinone 6 and 5-( 3- aminophenyl)-10,15,20-triphenylporphyrin 7 were prepared at first, and then they were directly used for condensation and afforded the target compound 1. The synthesis and characterization of compounds 1,4,5,8 and 9 were showed, and the structure and assembly properties with bifunctional guest( Bpy) of target compound 1 were also deliberately discussed in the report. |
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| Keywords: | bisporphyrin" ,bottom-up" method,molecular assembly,molecular device |
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