Crystal structures and magnetic properties of cyano-bridged 4f-3d complexes |
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Authors: | YAN Bing CHEN Zhida |
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Institution: | State Key Laboratory of Rare Earth Material Chemistry and Applications, College of Chemistry and Molecular Engineering,Peking University, Beijing 100871, China; Peking University-Hong Kong University Joint Laboratory of Rare Earth Materials and Bioinorgan |
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Abstract: | The most recent research progress in the fields of the crystal structure and magnetochemistry for rare earth-transition metal cyano-bridged complexes is reviewed in detail. The emphasis is put on the introduction to the research achievements of our group in this field, including all the types of complexes with different crystal structures in these systems such as dinuclear, trinuclear, one-dimensional chain and hydrogen-bonded network ion-pairs. At the same time a few examples of rare earth-transition metal molecular-based magnets have been found to exhibit excellent magnetochemical properties, such as the long-range magnetic ordering, the higher critical temperature Tc and the stronger coercive force. These results will be expected to promote the research development in this field. |
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Keywords: | molecular-based magnets cyano-bridged complexes 4f-3d crystal structures magnetic properties |
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