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铁液碱性熔渣脱砷
引用本文:刘守平,孙善长,等.铁液碱性熔渣脱砷[J].重庆大学学报(自然科学版),2001,24(4):106-110.
作者姓名:刘守平  孙善长
作者单位:重庆大学材料科学与工程学院!重庆400044
摘    要:中国储藏有大量的含砷铁矿。由于目前国内外钢铁生产流程中没有成熟的脱砷工艺。因此,开展钢铁脱砷技术研究对充分利用含砷铁矿资源,提高钢纯净度等有着迫切的现实意义。通过电阻炉上一系列实验研究,结果表明:CaO碱性熔渣对铁水可取得较好的脱砷效果;脱砷炉渣的X射线衍射分析表明CaO基碱性熔渣对铁液脱砷的产物是Ca3As2,脱砷反应为还原反应;脱砷的热力学条件是:W本系的氧位越低,铁注中硫含量越低、脱砷温度越高,熔渣碱度越高,脱砷效果越好。

关 键 词:脱砷  热力学  氧化钙基熔渣  铁液  碱性熔渣
文章编号:1000-582x(2001)04-0106-05
修稿时间:2001年2月28日

Study on the Dearsenization of Hot Metal Using CaO Basis Fluxes
LIU Shou ping,SUN Shan chang,ZHANG Bing huai,WENG Guang yuan.Study on the Dearsenization of Hot Metal Using CaO Basis Fluxes[J].Journal of Chongqing University(Natural Science Edition),2001,24(4):106-110.
Authors:LIU Shou ping  SUN Shan chang  ZHANG Bing huai  WENG Guang yuan
Abstract:There is plenty of iron ore with arsenic in China. Because a proven dearsenization technique does not come into existence in now iron making and steel making processes and it is necessary for developing the dearsenization of hot metal technologics. A serial of dearsenization experiments are carried out on electric resistance heated furnace, it's found that arsenic in hot metal can be removed by CaO basis fluxes. X ray qualitative analysis of CaO basis slag after dearsenization revealed that the product of hot metal dearsenization with CaO slag is Ca 3As 2 and the dearsenization reaction is a reducing one. The thermodynamic conditions of dearsenization of hot metal using CaO basis fluxes are that the lower of oxygen fraction pressure of the system and s] in hot metal, the higher of temperature of the system and basically of the slag, the dearsenization efficiency is better.
Keywords:dearsenization  thermodynamics  CaO basis fluxes  hot metal
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