| 血红素衍生物的合成、表征及其催化活性 |
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| 引用本文： | 符滇海,杨学强,林的的.血红素衍生物的合成、表征及其催化活性[J].中山大学学报(自然科学版),1999,38(4):44-47. |
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| 作者姓名： | 符滇海 杨学强 林的的 |
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| 作者单位： | 中山大学化学与化学工程学院 |
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| 摘 要： | 以氯化血红素为原料，合成了２种氯化血红素衍生物，用元素分析和ＦＡＢＭＳ，ＩＲ等谱对其结构进行表征，研究了它们对鲁米诺过氧化氢发光体系的催化活性．结果表明，氯化血红素分子的轴向配位基以及卟啉环骨架平面的２个乙烯基团的改变均对催化性能产生较大的影响
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| 关 键 词： | 化学发光 氯化血红素 鲁米诺 |
| 修稿时间： | 1998-08-21 |
Synthesis,Characterization and Catalytic Properties of the Heam Derivatives |
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| FU Dian haiSchool of Chemistry and Chemical Engineering,Zhongshan University,Guangzhou ,China,YANG Xue qiang,LIN De de,HUANG Li.Synthesis,Characterization and Catalytic Properties of the Heam Derivatives[J].Acta Scientiarum Naturalium Universitatis Sunyatseni,1999,38(4):44-47. |
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| Authors: | FU Dian haiSchool of Chemistry and Chemical Engineering Zhongshan University Guangzhou China YANG Xue qiang LIN De de HUANG Li |
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| Institution: | FU Dian haiSchool of Chemistry and Chemical Engineering,Zhongshan University,Guangzhou 510275,China,YANG Xue qiang,LIN De de,HUANG Li |
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| Abstract: | Two new heam derivatives were perpared Their structures were characterized by elemental analysis,FAB MS and IR Catalytic activity of the heam derivatives were studied in the reaction of luminol with hydrogen peroxide Results show that they have greater effect on the iron center of coordination groups and the change of two ethylene groups in the porphyrin |
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| Keywords: | chemiluminescencce heam luminol |
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