| 丙烯腈－丁二烯－苯乙烯共聚物的热降解动力学 |
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| 引用本文： | 冯仰婕,戴浩良,邹文樵,何东明. 丙烯腈－丁二烯－苯乙烯共聚物的热降解动力学[J]. 华东理工大学学报(自然科学版), 1994, 0(2) |
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| 作者姓名： | 冯仰婕 戴浩良 邹文樵 何东明 |
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| 作者单位： | 华东理工大学化学系 |
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| 摘 要： | 以热重分析法（ＴＧ、ＤＴＧ）为手段，对丙烯腈－丁二烯－苯乙烯共聚物（ＡＢＳ）的热降解动力学进行了研究。采用Ｓｃｓｔａｋ复杂机制进行了非线性拟合处理，得到了ＡＢＳ降解反应在不同升温速率β及不同转化率α下的活化能Ｅ、指前因子Ａ、反应级数等动力学参数。实验表明，参数的稳定性和重复性均很好。讨论了Ｓｅｓｔａｋ机制在求解动力学参数及描述降解反应机制中的优缺点。
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| 关 键 词： | 热降解；动力学；丙烯腈－丁二烯－苯乙烯共聚物 |
Kinetics of Thermal Degradation of Acfylonitrile-Butadiene-Styrene Copolymer |
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| Feng Yangjie,Dai Haoliang,Zou Wengqiao and He Dongming. Kinetics of Thermal Degradation of Acfylonitrile-Butadiene-Styrene Copolymer[J]. Journal of East China University of Science and Technology, 1994, 0(2) |
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| Authors: | Feng Yangjie Dai Haoliang Zou Wengqiao He Dongming |
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| Abstract: | Thermal degradation of polymer ABS was Studied by using the method of gravimetric analysis(TG,DTG).The Sestak's complex mechanism was used to do curve fitting,the computame results of kinetics parametcrs of activation energy E,preexponential A and the reaction degree have a good stability and repeatability.The superiority of the Sestak's mechanism to describe the ABS's degradation was also discussed. |
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| Keywords: | thermal degradation kinetics acrylonitrile-butadiene-styrene copolymer |
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