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高灵敏分光光度法测定微量铌
引用本文:朝君. 高灵敏分光光度法测定微量铌[J]. 萍乡高等专科学校学报, 1996, 0(4)
作者姓名:朝君
摘    要:基于铌钼杂多酸与丁基罗丹明B(BRB)和聚乙烯醇(PVA)可以形成稳定的离子缔合物,建立了在水相中直接测定微量铌的新方法.研究了缔合物的形成条件,方法的灵敏度高,其ε值为 7.5×10~5L·mol~(-1)·cm~(-1),已成功地应用于钢中铌的测定.

关 键 词:直接光度法  微量铌  高灵敏度

High Sensitive Spectrophotometric Method of Determing Trace Niobium
Chao Jun. High Sensitive Spectrophotometric Method of Determing Trace Niobium[J]. Journal of Pingxiang College, 1996, 0(4)
Authors:Chao Jun
Abstract:A new sensitive Spectrophotometric method of directly determing microamounts of Niobium is estabilished in water. The method is based on the formation of the ion -association complex of Molybdoniobic acid with Butyle Rhodamine B (BRB) in the presence of Polyvinyl Alcohol (PVA). The formation conditions was studied. The method has high sensitivty. e=7. 5x 105 1. mol-1.cm-1. Thhe method has been applied to determina tion of trace Niobium ni steel.
Keywords:direct spectrophotometry trace Niobium high sensitivity  
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