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| 无机硬模板HMS制备介孔碳工艺 | |
| 引用本文： | 李俊,王军,黄靓. 无机硬模板HMS制备介孔碳工艺[J]. 东华大学学报(自然科学版), 2010, 36(5) |
| 作者姓名： | 李俊 王军 黄靓 |
| 作者单位： | 1. 上海应用技术学院,化学与环境工程学院,上海,200235 2. 东华大学,环境科学与工程学院,上海,201620 3. 上海应用技术学院,化学与环境工程学院,上海,200235;东华大学,环境科学与工程学院,上海,201620 |
| 基金项目： | 上海市科委重点项目，上海应用技术学院基金 |
| 摘 要： | 以硅基介孔材料HMS(hexagonal mesoporous silica)为硬模板,以蔗糖为碳源,通过在N2气氛下高温碳化蔗糖,并利用氢氟酸除去模板制成介孔碳.分析了蔗糖填充方法、碳化温度和蔗糖与HMS的质量比对产品介孔碳结构的影响,并利用X衍射衍射(XRD)、扫描电镜(SEM)、透射电镜(TEM)、低温氮吸附-脱附及傅里叶红外(FT-IR)对样品进行了表征.结果表明,将一定量的蔗糖分两步填入HMS介孔中有利于碳源在模板孔道中均匀分布,有助于有序介孔碳的形成;碳化温度对最终产品碳的结构影响显著,适宜的碳化温度为800℃;蔗糖与HMS的质量比也直接影响产品的结构,两者的质量比过高或过低均难以形成介孔碳,最优比例为1.300∶1;所制成的介孔碳具有蠕虫状结构,比表面积可达2433m2/g. |
| 关 键 词： | 介孔材料HMS 硬模板 蔗糖 介孔碳 工艺 |
The Preparation Process of Mesoporous Carbon with Mesoporous Material HMS as Template |
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| LI Jun,WANG Jun,HUANG Liang. The Preparation Process of Mesoporous Carbon with Mesoporous Material HMS as Template[J]. Journal of Donghua University, 2010, 36(5) | |
| Authors: | LI Jun WANG Jun HUANG Liang |
| Affiliation: | LI Jun1,WANG Jun2,HUANG Liang1,2( 1.School of Chemical , Enviromental Engineering,Shanghai Institute of Technology,Shanghai 200235,China,2. School of Environmental Science , Engineering,Donghua University,Shanghai 201620,China) |
| Abstract: | A series of ordered mesoporous carbons were synthesized with sucrose as the carbon precursor and HMS (hexagonal mesoporous silica) as template in the presence of N2 and removing the template with hydrofluoric acid. The influence of the impregnation method of sucrose, the carbonization temperature and the mass ratios of sucrose to HMS on the structure of the carbon products were analyzed. XRD, SEM, TEM, N2 adsorption-desorption and FT-IR were used to characterize the products. Results showed that the two-ste... |
| Keywords: | mesoporous material HMS hard template sucrose mesoporous carbon process |
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