| Syntheses and Reactions of Novel Oxidized Variants of Sterically-Crowded Chalcogenocarbonyl Compounds |
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| 引用本文： | Kazuaki Shimada. Syntheses and Reactions of Novel Oxidized Variants of Sterically-Crowded Chalcogenocarbonyl Compounds[J]. 复旦学报(自然科学版), 2005, 44(5): 791-792 |
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| 作者姓名： | Kazuaki Shimada |
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| 作者单位： | Department of Chemical Engineering, Faculty of Engineering, hoate University Morioka, Iwate 020-8551, Japan |
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| 摘 要： | 1 Introduction d-Camphor and their derivatives have been widely used as chiral auxiliaries and synthons for organic synthesis, and our attempts are focused onto the new functionalization of these skeletons through the generation of oxidized variants of thiones and selones through in situ generation of novel oxidized variants of bornane-2-thiones and selones. In this paper, a novel generation and chemical conversion of these reactive intermediates are presented.1Introductiond-Camphor andtheir d…
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| 关 键 词： | 合成方法 手性辅助 有机化学 氧化物 化学转化 |
| 文章编号： | 0427-7104（2005）05-0791-02 |
| 收稿时间： | 2005-08-05 |
| 修稿时间： | 2005-08-05 |
Syntheses and Reactions of Novel Oxidized Variants of Sterically-Crowded Chalcogenocarbonyl Compounds |
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| Kazuaki Shimada. Syntheses and Reactions of Novel Oxidized Variants of Sterically-Crowded Chalcogenocarbonyl Compounds[J]. Journal of Fudan University(Natural Science), 2005, 44(5): 791-792 |
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| Authors: | Kazuaki Shimada |
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| Abstract: | d-Camphor and their derivatives have been widely used as chiral auxiliaries and synthons for organic synthesis, and our attempts are focused onto the new functionalization of these skeletons through the generation of oxidized variants of thiones and selones through in situ generation of novel oxidized variants of bornane-2- thiones and selones. In this paper, a novel generation and chemical conversion of these reactive intermediates are presented. |
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| Keywords: | sterically-crowded thione sterically-crowded selone thione S-sulfide dithiirane thione S-imide |
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