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A-B型甲基丙烯酸酯嵌段共聚物的合成
引用本文:戴李宗,邹友思,刘秀彩,潘容华. A-B型甲基丙烯酸酯嵌段共聚物的合成[J]. 厦门大学学报(自然科学版), 1996, 0(2)
作者姓名:戴李宗  邹友思  刘秀彩  潘容华
摘    要:A-B型甲基丙烯酸酯嵌段共聚物的合成戴李宗,邹友思,刘秀彩,潘容华(化工系)基因转移聚合[‘j(GTP)作为一种极性单体的加聚方式,由于其许多的优点而受到日益广泛的重视.自该聚合方法发现以来的十余年时间内,人们已将注意力由对其机理等基础研究逐步转向新...


Synthesis of A-B Diblock Copolymer of Methacrylate
Dai Lizong,Zou Yousi,Liu Xiucai, Pan Ronghua. Synthesis of A-B Diblock Copolymer of Methacrylate[J]. Journal of Xiamen University(Natural Science), 1996, 0(2)
Authors:Dai Lizong  Zou Yousi  Liu Xiucai   Pan Ronghua
Affiliation:Dept.of Chem. Engr.
Abstract:roup transfer block copolymerization of C7-9 Methacrylate and Methyl methacrylate was investigated by using 1- methoxy -1- (trimethylsiloxly) - 2 - methyl- 1- propene (MTS) and tetrabutylammonium bibenzoate (TBABB) as initiaor and catalyst; respectively.The infuerce of temperature and [Cat]/[I] on GTP was discussed. According to Arrhenius's figuration;the activation energy of C7-9methacrylate GTP (Ea=48. 3 kJ/mol) was Counted.
Keywords:Group transfer polymerization  Block copolymer  Polymethacrylate  Synthesis
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