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异丙醇胺-水体系的汽液平衡
引用本文:范茏,张雅明. 异丙醇胺-水体系的汽液平衡[J]. 南京工业大学学报(自然科学版), 2001, 23(2): 45-48
作者姓名:范茏  张雅明
作者单位:南京化工大学化工学院,
摘    要:采用鼓泡式平衡釜测定了一异丙醇胺-水、一异丙醇胺-二异丙醇胺以及水-二异丙醇胺等二元体系在65℃、80℃、95℃时的恒温汽液平衡数据。用vanLaar、Margules、NRTL、Wilson、UNIQUAC等5种方程对其进行关联,求出模型参数,利用所得模型参数计算相应的汽相组成,并与实测值比较,二者符合良好。

关 键 词:鼓泡式平衡釜 一异丙醇胺 二异丙醇胺 汽液平衡
文章编号:1007—7537(2001)02—0045—04
修稿时间:2000-07-11

STUDY ON VAPOR-LIQUID EQUILIBRIUM OF SYSTEMS CONTAINING ISOPROPANOLAMINES AND WATER
FAN Long,Zhang Yaming. STUDY ON VAPOR-LIQUID EQUILIBRIUM OF SYSTEMS CONTAINING ISOPROPANOLAMINES AND WATER[J]. Journal of Nanjing University of Technology, 2001, 23(2): 45-48
Authors:FAN Long  Zhang Yaming
Abstract:The vapor-liquid equilibrium(VLE) data of monoisopropanolamine(MIPA) and water, MIPA and diisopropanolamine(DIPA), and DIPA and water systems were measured at 65 ℃,80 ℃ and 95 ℃ by a bubbling equilibrium still. Five activity coefficient models: Margules, van Laar, Wilson, NRTL, and UNIQUAC, were used to correlate the VLE data of these binary systems to obtain the binary parameters. With these parameters, vapor compositions were calculated and compared with those corresponding experimental data. The results are in good agreement.
Keywords:bubbling equilibrium still monoisopropanolamine diisopropanolamine vapor-liquid equilibrium
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