| 不对称星形偶联反应的动力学分析 |
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| 引用本文： | 胡孝东,颜德岳,徐祥铭,王佛松. 不对称星形偶联反应的动力学分析[J]. 上海交通大学学报, 1988, 0(3) |
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| 作者姓名： | 胡孝东 颜德岳 徐祥铭 王佛松 |
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| 作者单位： | 上海交通大学应用化学系，上海交通大学应用化学系，上海交通大学应用化学系，中科院应用化学研究所 上海交通大学兼职教授 |
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| 摘 要： | 通过严格求解不对称星形偶联反应的动力学微分方程组,得到了不对称星形聚合物的各种分子参数与两种被偶联预聚物的分子参数之间的关系。结果表明,不论两种被偶联预聚物的起始分布如何,只要生成的不对称星形聚合物的臂数足够大,其最终分布将趋于均一。
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| 关 键 词： | 动力学 偶联 星形聚合物 |
Kinetic Analysisof Dissymetric Star Coupling Reaction |
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| Hn Xiaodong Yan Deyue Xu Xiangming Wang Fosong. Kinetic Analysisof Dissymetric Star Coupling Reaction[J]. Journal of Shanghai Jiaotong University, 1988, 0(3) |
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| Authors: | Hn Xiaodong Yan Deyue Xu Xiangming Wang Fosong |
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| Affiliation: | Hn Xiaodong Yan Deyue Xu Xiangming Wang Fosong |
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| Abstract: | In this paper,the dissymetric star coupling reaction is studied by solvingthe set ofkinetic differential equations.The relationship between the parametersof the dissymetric star-shaped polymer and those of the prepolymers has beenobtained.It is concluded that the more arms the star-shaped polymer has,the more homogeneous it is;when the degree of branching is large enough,thestar-shaped polymer follows the normal distribution in spite of the dispersity ofprepolymers. |
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| Keywords: | kinetics coupling star-shaped polymer |
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