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轻质碳酸钙在氮气气氛中的热分解动力学研究
引用本文:徐苏利,董俊. 轻质碳酸钙在氮气气氛中的热分解动力学研究[J]. 贵州大学学报(自然科学版), 2011, 28(3): 34-37
作者姓名:徐苏利  董俊
作者单位:贵州大学理学院化学系,贵州贵阳,550025
摘    要:用热分析技术研究了轻质碳酸钙(PCC)在氮气气氛中热分解过程。结果表明,轻质碳酸钙在氮气气氛中为一步分解反应。用多元非线性回归法对轻质碳酸钙的热分解过程进行了动力学分析,得出最概然机理、活化能、指前因子等动力学三因子。

关 键 词:轻质碳酸钙  TG-DSC  多元非线性动力学回归

Kinetics of Thermal Decomposition of PCC in Nitrogen
XU Su-li,DONG Jun. Kinetics of Thermal Decomposition of PCC in Nitrogen[J]. Journal of Guizhou University(Natural Science), 2011, 28(3): 34-37
Authors:XU Su-li  DONG Jun
Affiliation:(Department of Chemistry,College Of Science,Guizhou University,Guiyang 550025,China)
Abstract:The thermal decomposition processes PCC was studied in Nitrogen using TG-DSC.The result shows the thermal decomposition processed of PCC in Nitrogen is a one step.The multivariate non-1inear regression method in dynamic analysis to thermal decomposition of PCC was used,then factors of kinetics were obtained such as the most probable mechanism function,the activation energy,the pre-exponential factor.
Keywords:PCC  TG-DSC  multivariate non-linear regression
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