| 超分子C14H14N4O8的合成及结构表征 |
| |
| 引用本文： | 祖丽皮亚·阿不力孜,王英波,满苏尔·那斯尔,张艳慧.超分子C14H14N4O8的合成及结构表征[J].西南师范大学学报(自然科学版),2012,37(3):49-52. |
| |
| 作者姓名： | 祖丽皮亚·阿不力孜 王英波 满苏尔·那斯尔 张艳慧 |
| |
| 作者单位： | 新疆师范大学化学化工学院,乌鲁木齐,830054 |
| |
| 基金项目： | 新疆师范大学无机化学重点学科建设资助项目 |
| |
| 摘 要： | 以反丁烯二酸和咪唑为原料,采用缓慢蒸发溶剂法合成了新的有机加合物C14H14N4O8,并获得了其单晶体.通过红外、热化学分析、X-射线单晶衍射等技术对该加合物进行了结构测定和性质表征.晶体中分子通过分子间氢键相互连接构成超分子网络结构.该加合物属于三斜晶系,P-1空间群,a=0.746 77(15), b=7.736 3(15),c=8.405 5(17),α=69.73(3)°,β=80.40(3)°,γ=66.19(3)°,Z=1,V=416.75(14)A3,D=1.468 (mg/m3),F(000)=190.
|
| 关 键 词： | 单晶 氢键 超分子 分子设计 |
Syntehsis of the Supramolecule C14H14N4O8 and Characterization of Its Structure |
| |
| ZULIPIYA Abulizi
,
WANG Ying-bo
,
MANSUER Nasier
,
ZHANG Yan-hui.Syntehsis of the Supramolecule C14H14N4O8 and Characterization of Its Structure[J].Journal of Southwest China Normal University(Natural Science),2012,37(3):49-52. |
| |
| Authors: | ZULIPIYA Abulizi WANG Ying-bo MANSUER Nasier ZHANG Yan-hui |
| |
| Institution: | College of Chemistry and Chemical Engineering,Xinjiang Normal University,Urumqi 830054,China |
| |
| Abstract: | A new organic adduct,C14H14N4O8,was synthesized with fumaric acid and imidazole as the raw materials,using the slow solvent evaporation method.Its single crystal was obtained through slow evaporation of the saturated water solution.The structure of this adduct was characterized by FTIR,TG and X-ray single crystal diffraction.In the crystal,the molecules formed a supramolecular network structure by intermolecular hydrogen bonds.The adduct was of the triclinic crystal system,space group P1,with a=7.467 7(15),b=7.736 3(15),c=8.405 5(17),α=69.73(3)°,β=80.40(3)°,γ=66.19(3)°,Z=1,V=416.75(14)3,D=1.468(mg/m3) and F(000)=190. |
| |
| Keywords: | single crystal hydrogen bonds supramolecule crystal design |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
| 点击此处可从《西南师范大学学报(自然科学版)》浏览原始摘要信息 |
| 点击此处可从《西南师范大学学报(自然科学版)》下载免费的PDF全文 |
|
