| 无隔膜电解槽中对苯醌电合成的研究 |
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| 引用本文： | 赵玉娥,张恒彬,孙家锺. 无隔膜电解槽中对苯醌电合成的研究[J]. 吉林大学学报(理学版), 2002, 40(2): 215-217 |
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| 作者姓名： | 赵玉娥 张恒彬 孙家锺 |
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| 作者单位： | １. 吉林大学化学科学学院， 长春 130023； 2. 吉林大学理论化学研究所， 长春 1300233.北京联合大学化学工程学院, 北京 100023 |
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| 摘 要： | 在无隔膜电解槽中， 以Cu２＋离子为电解媒质， 铜板作阳极， 石墨作阴极， 对苯的 间接电氧化进行研究. 实验结果表明， 苯的电解产物对苯醌的产率和电流效 率均比无隔膜电解槽中苯的直接电氧化有较大的提高.
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| 关 键 词： | 苯 对苯醌 间接电氧化 无隔膜电解槽 |
| 文章编号： | 1671-5489(2002)02-0215-03 |
| 收稿时间： | 2001-11-22 |
| 修稿时间： | 2001-11-22 |
Studies on Electrosynthesis of Para Quinone in an Undivided Electrolytic Cell |
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| ZHAO Yu-e. Studies on Electrosynthesis of Para Quinone in an Undivided Electrolytic Cell[J]. Journal of Jilin University: Sci Ed, 2002, 40(2): 215-217 |
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| Authors: | ZHAO Yu-e |
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| Affiliation: | 1. College of Chemistry, Jilin University, Changchun 130023, China;2. Institute of Theoritical Chemistry, Jilin University, Changchun 130023, China3. College of Chemical Engineering, Beijing Union University, Beijin g 100023， China; |
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| Abstract: | In an undivided electrolytic cell and with benzene as the starting material, Cu 2 ions as electrolytic medium, Cu as the anode material and graphite as the cathode material, the synthesis of para quinone via the indirect electrooxidation of benzene was studied. The experimental results demonstrate that the yield of electrolytic products para quinone and current efficiency were higher than the corresponding ones for direct electrooxidation of benzene in the divided electrolytic cell. |
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| Keywords: | benzene para quinone indirect electrooxidation undivided electrolytic cell |
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