| Recent Advances in the Development of Polymer-supported Phosphines |
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| 作者姓名： | Patrick H. Toy Helen Song He Cathy Kar-Wing Kwong |
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| 作者单位： | Deparment of Chemistry, The University of Hang Kong, Hang Kong, China |
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| 摘 要： | 1 Introduction Recent years have seen a growing use of polymer-supported reagents by organic chemists in traditional solution-phase synthesis.Of the many reagents supported by polymers available, variations of triphenylphosphine are among the most broadly used. This is because triphenylphosphine is not only a reagent in a wide range of organic reactions~(1]), but it also serves as a ligand in many organometallic reagents~(2]).Most importantly, polymer-supported triphenylphosphine affords the…
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| 关 键 词： | 聚合体 磷化氢 Baylis-Hillman反应 有机化学 合成方法 |
| 文章编号： | 0427-7104（2005）05-0833-02 |
| 收稿时间： | 2005-08-09 |
| 修稿时间： | 2005-08-09 |
Recent Advances in the Development of Polymer-supported Phosphines |
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| Patrick H. Toy Helen Song He Cathy Kar-Wing Kwong.Recent Advances in the Development of Polymer-supported Phosphines[J].Journal of Fudan University(Natural Science),2005,44(5):833-834. |
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| Authors: | Patrick H Toy Helen Song He Cathy Kar-Wing Kwong |
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| Abstract: | Recent years have seen a growing use of polymer-supported reagents by organic chemists in traditional solution-phase synthesis. Of the many reagents supported by polymers available, variations of triphenylphosphine are among the most broadly used. This is because triphenylphosphine is not only a reagent in a wide range of organic reactions, but it also serves as a ligand in many organometallic reagents. Most importantly, polymer-supported triphenylphosphine affords the great advantage that the byproduct of most reactions involving it, triphenylphosphine oxide, can be easily removed. |
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| Keywords: | J andaJel phosphines organocatalysis Baylis-Hillman reactions |
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