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Kinetic Parameters of Thermal Degradation of Polymers
引用本文:朱新生,程嘉祺. Kinetic Parameters of Thermal Degradation of Polymers[J]. 东华大学学报(英文版), 2003, 20(1)
作者姓名:朱新生  程嘉祺
作者单位:School of Materials Engineering,Suzhou University,Suzhou,215021,School of Materials Engineering,Suzhou University,Suzhou,215021
摘    要:The derivative expressions between activation energy(E) and the temperature at the maximum mass lossrate(T_(max)) and between activation energy (E) andexponent (N) were deduced in the light of Arrheniustheory. It was found that the increase of activationenergy results in the decrease of exponent and the


Kinetic Parameters of Thermal Degradation of Polymers
ZHU Xin-sheng,CHENG Jia-qiSchool of Materials Engineering,Suzhou University,Suzhou. Kinetic Parameters of Thermal Degradation of Polymers[J]. Journal of Donghua University, 2003, 20(1)
Authors:ZHU Xin-sheng  CHENG Jia-qiSchool of Materials Engineering  Suzhou University  Suzhou
Affiliation:School of Materiols Engineering,Suzhou University,Suzhou,215021
Abstract:The derivative expressions between activation energy (E) and the temperature at the maximum mass loss rate(Tmax) and between activation energy (E) and exponent (N) were deduced in the light of Arrhenius theory. It was found that the increase of activation energy results in the decrease of exponent and the increase of Tmax. The kinetic parameters were involved in the analysis of the thermal degradation of several polymers. The degradation kinetics of these polymers well complied with the prediction of the derivative expressions for the polymer degradation with single mechanism dominated.
Keywords:Activation energy   exponent   maximum mass loss rate   thermal degradation
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