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Mn-Cu耐候钢在模拟工业大气环境下的腐蚀行为
引用本文:吴红艳,杜林秀,刘相华,张熙. Mn-Cu耐候钢在模拟工业大气环境下的腐蚀行为[J]. 东北大学学报(自然科学版), 2011, 32(10): 1418-1422. DOI: -
作者姓名:吴红艳  杜林秀  刘相华  张熙
作者单位:1. 东北大学轧制技术及连轧自动化国家重点实验室,辽宁沈阳,110819
2. 本钢集团有限公司技术中心,辽宁本溪,117000
基金项目:国家自然科学基金资助项目(51034009,50974039)
摘    要:利用干湿交替加速腐蚀实验和电化学实验研究了实验钢在模拟工业大气环境下的腐蚀演化行为.结果表明,在腐蚀初期腐蚀速度随循环周期的增加而增大,在后期随循环周期的增加而降低,耐候钢的腐蚀速度与SPA-H钢相当但低于16Mn钢.在腐蚀初期,细晶粒耐候钢比粗晶粒腐蚀速度快,在后期腐蚀速度基本一致.耐候钢锈层分为内外两层,内锈层致密主要由α-FeOOH和少量γ-Fe2O3组成,晶粒尺寸对腐蚀产物的组成影响不大.16Mn钢锈层主要由α-FeOOH,γ-Fe2O3和Fe3O4组成.在腐蚀后期,Cu的作用使耐候钢的耐腐蚀性能优于16Mn钢.电化学实验表明,腐蚀产物促进阴极过程,抑制阳极过程.细晶粒有利于保护性内锈...

关 键 词:耐候钢  工业大气环境  干湿交替  锈层结构  电极化曲线  

Corrosion Behavior of Mn-Cu Weathering Steel in Simulated Industrial Atmosphere Environment
WU Hong-yan,DU Lin-xiu,LIU Xiang-hua,ZHANG Xi. Corrosion Behavior of Mn-Cu Weathering Steel in Simulated Industrial Atmosphere Environment[J]. Journal of Northeastern University(Natural Science), 2011, 32(10): 1418-1422. DOI: -
Authors:WU Hong-yan  DU Lin-xiu  LIU Xiang-hua  ZHANG Xi
Affiliation:WU Hong-yan1,DU Lin-xiu1,LIU Xiang-hua1,ZHANG Xi2(1.State Key Laboratory of Rolling and Automation,Northeastern University,Shenyang 110819,China,2.Technology Center,Benxi Iron & Steel Group Corp.,Benxi 117000,China.)
Abstract:Corrosion evolution of Mn-Cu weathering steels in a simulated industrial atmosphere environment was studied by wet/dry cyclic accelerated corrosion test and electrochemical test.The results showed that the corrosion rate increases with the wet/dry cycles in the initial stage of the test and decreases in the latter stage of the test.The corrosion rate of weathering steel is near to SPA-H steel and lower than that of 16Mn steel.In the early,the corrosion rate of fine grain weathering steel is faster than that...
Keywords:weathering steel  industrial atmosphere environment  wet/dry cyclic  structure of rust layer  electric polarization curve  
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