| 一个新颖的镉配合物的合成、结构、热稳定性和发光性能研究 |
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| 引用本文： | 朱东升,希迪. 一个新颖的镉配合物的合成、结构、热稳定性和发光性能研究[J]. 吉林师范大学学报(自然科学版), 2014, 0(4): 15-18 |
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| 作者姓名： | 朱东升 希迪 |
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| 作者单位： | 东北师范大学 化学学院,吉林 长春,130024 |
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| 基金项目： | 吉林省科技发展计划项目 |
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| 摘 要： | 用含氮配体Mdcp和柔性的二元羧酸戊二酸为混合配体合成了一个新型的镉配合物[Cd(Mdcp)(GTC)]n(1),并且通过元素分析、热失重分析、红外和X-射线单晶衍射对配合物(1)进行了表征,结构表明此配合物为新颖的二维层状结构,并且通过氢键作用形成三维的网状结构,热失重曲线清晰的表明了各个温度区间内的失重情况.此外研究了配合物(1)的荧光发光性质.
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| 关 键 词： | 镉 晶体结构 热失重分析 荧光 |
Synthesis,Structure,Thermal Stability and Luminescent Properties of One Novel Cadmium Compound |
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| ZHU Dong-sheng,Sougoule Aboubacar Sidiki. Synthesis,Structure,Thermal Stability and Luminescent Properties of One Novel Cadmium Compound[J]. Jilin Normal University Journal(Natural Science Edition), 2014, 0(4): 15-18 |
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| Authors: | ZHU Dong-sheng Sougoule Aboubacar Sidiki |
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| Affiliation: | ZHU Dong-sheng, Sougoule Aboubacar Sidiki ( College of Chemistry, Northeast Normal University, Changchun 130024, China) |
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| Abstract: | A novel metal-organic coordination compound [ Cd（ Mdcp ）（ GTC ）]n（ 1 ）[ Mdcp = 2-（ 3-methoxyphenyl）-1H-imidazo[4,5-f][1,10]phenanthroline,GTC = pentanedioic acid]has been synthesized by hydrothermal reactions and characterized by elemental analysis,thermogravimetric（ TG） analysis,infrared spectrum（ IR）and single-crystal X-ray diffraction. The single-crystal X-ray diffraction result reveals that the compound（1）exhibits two-dimensional（2D）layer architecture which is linking to 3D structure by the H-bond intersections. The TG analysis result shows the courses of weight loss. We also study the luminescent properties of the compound（1）. |
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| Keywords: | cadmium crystal structures thermal stability analysis fluorescence |
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