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The electrical conductivity of H2O at 0.21– 4.18 GPa and 20–350°C
Authors:Haifei Zheng  Hongsen Xie  Yousheng Xu  Maoshuang Song  Jie Guo  Yueming Zhang
Institution:(1) Institute of Geochemistry, Chinese Academy of Sciences, 550002 Guiyang, China;(2) Present address: Department of Geology, Peking University, 100871 Beijing, China
Abstract:The electrical conductivity of H2O in solid and liquid phases has been measured at 0.21–4.18 GPa and 20–350°C. The results indicate: (I) different phases of H2O in solid have different relations between electrical conductivity and temperature and pressure. The conductivity changes continuously with temperature, but discontinuously with the pressure between 2.11 and 2.58 GPa, which corresponds to the transforming pressure between ice (VI) and ice (VII);(II) the amductivity of H2O in liquid all increases with temperature and pressure, but there are discontinuities at pressures between 0.57 and 0.9 GPa, and between 2.11 and 2.58 GPa, which are also consistent with the polyrnorph of ice (ice (V), ice (VI) and ice (VII)). This reflects that H2O in liquid at different pressures has quite different properties of electron chemistry. It is probably the important reason that causes the layers with high electrical conductivity and low velocity in the earth’s ceust and upper mantle.
Keywords:high temperature and high pressure  ice  water  electrical conductivity
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