| Fe~(3+)交换大孔阳离子树脂催化剂的催化反应规律研究 |
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| 引用本文： | 黄亚侬,曹声春.Fe~(3+)交换大孔阳离子树脂催化剂的催化反应规律研究[J].湖南文理学院学报(自然科学版),1999(4). |
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| 作者姓名： | 黄亚侬 曹声春 |
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| 作者单位： | 常德师范学院化学系!常德，415000，湖南大学化学化工学院!长沙，410082 |
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| 摘 要： | 讨论了将Fe3+交换的大孔阳离子树脂用于苯液相一步健代氧化合成苯酚，并对反应温度、H2O2浓度、原料料比、反应时间、催化剂用量等因素对苯酚收率和选择性的影响规律进行了考察，提出了可能的反应机理。
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| 关 键 词： | 苯 苯酚 液相氧化 树脂催化剂 |
A Study on the Catalytic Roles of Fe~(3+) Exchanged Macropore Cation Resin Catalyst |
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| Huang Yanong.A Study on the Catalytic Roles of Fe~(3+) Exchanged Macropore Cation Resin Catalyst[J].Journal of Hunan University of Arts and Science:Natural Science Edition,1999(4). |
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| Authors: | Huang Yanong |
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| Abstract: | The iron exchanged macropore cation resin was used as a catalyst in the direct catalytic oxidation of liquidphase benzene to phenol. The effects of reaction temperature, time, H2O2 conentraion, material ratio and catalyst amount on the yield and selectivity of phenol were investigated. Possible reaction mechanism was proposed. |
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| Keywords: | benzene phenol liquid-phase oxidation resin catalyst |
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