| 一类新型含氮冠醚的合成 |
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| 引用本文： | 鲁统部,彭新煜,李晓燕.一类新型含氮冠醚的合成[J].中山大学学报(自然科学版),1999,38(2):124-126. |
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| 作者姓名： | 鲁统部 彭新煜 李晓燕 |
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| 作者单位： | 中山大学化学与化学工程学院，中山大学测试中心 |
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| 摘 要： | 采用二缩三乙二醇二对甲苯磺酰基及三缩四乙二醇二氯醚与Ｎ对甲苯磺酰基取代的多乙撑多胺（三乙撑四胺和四乙撑五胺）二钠盐在无水二甲基甲酰胺中回流反应４～５ｈ，得到４个新的含氮冠醚化合物：Ｎ４Ｏ２１８冠６，Ｎ４Ｏ３２１冠７，Ｎ５Ｏ２２１冠７和Ｎ５Ｏ３２４冠８，收率５７％～８３％．
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| 关 键 词： | N_4O_2-18-冠-6 N_4O_3-21-冠-7 N_5O_2-21-冠-7 N_5O_3-24-冠-8 合成 |
Synthesis of Four New Binucleating Polyoxa Polyaza Macrocyclic Compounds |
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| LU Tong-bu ,PENG Xin-yu,LI
Xiao-yan,JI Liang-nian
School of Chemistry and Chemical Engineering,Zhongshan University,Guangzhou , China.Synthesis of Four New Binucleating Polyoxa Polyaza Macrocyclic Compounds[J].Acta Scientiarum Naturalium Universitatis Sunyatseni,1999,38(2):124-126. |
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| Authors: | LU Tong-bu PENG Xin-yu LI
Xiao-yan JI Liang-nian
School of Chemistry and Chemical Engineering Zhongshan University Guangzhou China |
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| Institution: | LU Tong-bu ,PENG Xin-yu,LI
Xiao-yan,JI Liang-nian
School of Chemistry and Chemical Engineering,Zhongshan University,Guangzhou 510275, China |
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| Abstract: | Four new binucleating polyoxa polyaza macrocyclic compounds, 1,4,7,10 tetratosyl 1,4,7,10 tetraaza 13,16 dioxacyclooctadecane;1,4,7,10 tetratosyl 1,4,7,10 tetraaza 13,16, 19 trioxacycloheneicosane;1,4,7,10,13 pentatosyl 1,4,7,10,13 pentaaza 16,19 dioxacycloheneicosane;1,4,7,10,13 pentatosyl 1,4,7,10,13 pentaaza 16,19,22 trioxacyclotetracosane were synthesized and characterized by elemental analyses, 1H NMR, MS and IR spectra |
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| Keywords: | binucleating polyoxa polyaza macrocyclic compounds synthesis |
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