| 一种新型聚醚多元醇的合成及其诱导期研究 |
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| 引用本文： | 王晓,顾尧,冯新武.一种新型聚醚多元醇的合成及其诱导期研究[J].青岛化工学院学报(自然科学版),2008(5):437-440. |
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| 作者姓名： | 王晓 顾尧 冯新武 |
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| 作者单位： | 青岛科技大学橡塑材料与工程教育部重点实验室,山东青岛266042 |
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| 摘 要： | 用自制的双金属氰化物络合物催化剂（DMC）合成了以酚醛树脂为起始剂的聚醚多元醇。并利用温度与时间曲线分析合成反应的诱导期,考察了起始温度、催化剂浓度、起始剂用量以及单体浓度等对诱导期及最大反应压力的影响,并表征了酚醛聚醚多元醇的结构。结果表明,酚醛树脂中羟基浓度0.0037 mol.L^-1、环氧丙烷18 mL（占物料总质量的95%）、催化剂DMC质量分数470×10^-6%及温度110℃左右为最佳反应条件。
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| 关 键 词： | 双金属催化剂 酚醛树脂 聚醚 诱导期 |
Studies of the Synthesis Conditions of a New Type Polyether Polyols and Their Effects on its Induction Periods |
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| WANG Xiao,GU Yao,FENG Xin-wu.Studies of the Synthesis Conditions of a New Type Polyether Polyols and Their Effects on its Induction Periods[J].Journal of Qingdao Institute of Chemical Technology(Natural Science Edition),2008(5):437-440. |
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| Authors: | WANG Xiao GU Yao FENG Xin-wu |
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| Institution: | (Key Laboratory of Rubber plastics, Ministry of Education Qingdao University of Science and Technology, Qingdao 266042,China) |
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| Abstract: | The polyether polyols was synthesized by using phenolic resins as the initiators and the self-made double metal cyanide as the catalyst. The reaction temperature and pressure changes were reeorded by using a computer. The effects of the reaction conditions on induction period and maximum reaetion pressure were studied. It was found that the optimum reaction condition was at a 0. 003 7 mol · L^-1 of the hydroxyl concentration and PO15mL in phenolic resin a 470X 10 6%0 mass fraction of DMC and a initiation temperature of about 110℃. The synthesized phenolic polyether polyols was characterized by FTIR. |
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| Keywords: | double metal cyanide catalyst phenolic resin polyether induction period characterization |
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