| L-谷氨酸-5-甲酯金属铜化合物的合成、表征及生物活性 |
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| 引用本文： | 金龙飞,范昕,金呈之,王彦荣,吴勇飞,吴腊梅.L-谷氨酸-5-甲酯金属铜化合物的合成、表征及生物活性[J].中南民族大学学报(自然科学版),2012,31(2):15-19. |
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| 作者姓名： | 金龙飞 范昕 金呈之 王彦荣 吴勇飞 吴腊梅 |
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| 作者单位： | 中南民族大学化学与材料科学学院,武汉,430074 |
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| 基金项目： | 湖北省自然科学基金重点资助项目(2008CDA067) |
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| 摘 要： | 通过L-谷氨酸-5-甲酯与Cu（CH3COO）2.H2O反应,合成了相应的金属铜化合物Cu（C6H10NO4）2].对L-谷氨酸-5-甲酯金属铜化合物的晶体进行了X-射线单晶衍射测定.结果表明：L-谷氨酸-5-甲酯金属铜化合物属单斜晶系,P2（1）空间群,其中a=9.5883（19）,b=5.1521（10）,c=15.562（3）;β=98.65（3）°.抗菌筛选数据表明,L-谷氨酸-5-甲酯金属铜化合物对枯草芽胞杆菌具有较好的抑制作用.
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| 关 键 词： | L-谷氨酸-5-甲酯金属铜化合物 合成 晶体结构分析 抗菌活性 |
Synthesis,Characterization and Biological Activity of Metal Copper Complex with 5-Methyl-L-Glutamate |
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| Jin Longfei,Fan Xin,Jin Chengzhi,Wang Yanrong,Wu Yongfei,Wu Lamei.Synthesis,Characterization and Biological Activity of Metal Copper Complex with 5-Methyl-L-Glutamate[J].Journal of South-Central Univ for,2012,31(2):15-19. |
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| Authors: | Jin Longfei Fan Xin Jin Chengzhi Wang Yanrong Wu Yongfei Wu Lamei |
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| Institution: | (College of Chemistry and Materials Science,South-Central University for Nationalities,Wuhan 430074,China) |
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| Abstract: | A novel copper complex Cu(C6H10NO4)2] was synthesized via the reaction of 5-methyl-L-glutamate with Cu(CH3COO)2·H2O in water solution and its structure of Cu(C6H10NO4)2] was determined by X-ray diffraction.The results indicated that it crystallizes in the monoclinic system and spaces in group P2(1) with a= 9.5883(19) ,b = 5.1521(10) ,c = 15.562(3);β= 98.65(3) °.Moreover,Cu(C6H10NO4)2] has strong antimicrobial activity against Bacillus subtilis. |
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| Keywords: | 5-methyl-L-glutamate metal copper complex(Cu(C6H10NO4)2) synthesis ctistal strcture analysis antibacterial activity |
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