| 新型N2O2杂大环双乙酸修饰电极的研究 |
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| 引用本文： | 李胜利,张胜义,吴杰颖,金葆康,孙昕. 新型N2O2杂大环双乙酸修饰电极的研究[J]. 安徽大学学报(自然科学版), 2005, 29(1): 73-76 |
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| 作者姓名： | 李胜利 张胜义 吴杰颖 金葆康 孙昕 |
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| 作者单位： | 安徽大学,化学化工学院,安徽,合肥,230039;安徽医科大学,临床肿瘤研究所,安徽,合肥,230022 |
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| 基金项目： | 国家自然科学基金;50272001,20071001; |
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| 摘 要： | 利用作者合成的N2O2杂大环双乙酸参与邻苯二胺的电化学聚合,成功地制备了性能优良的修饰电极。通过循环伏安等实验研究了电极的电化学性能。电极用于阳极溶出伏安法测定血清中的痕量铜,取得满意结果。
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| 关 键 词： | 杂大环 聚邻苯二胺 修饰电极 铜 |
| 文章编号： | 1000-2162(2005)01-0073-04 |
A study of modified electrode with novel N2O2 heteromacrocycle diacetic acid |
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| LI Sheng-li,ZHANG Sheng-yi,WU Jie-ying,JIN Bao-kang,SUN Xin. A study of modified electrode with novel N2O2 heteromacrocycle diacetic acid[J]. Journal of Anhui University(Natural Sciences), 2005, 29(1): 73-76 |
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| Authors: | LI Sheng-li ZHANG Sheng-yi WU Jie-ying JIN Bao-kang SUN Xin |
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| Affiliation: | LI Sheng-li~1,ZHANG Sheng-yi~1,WU Jie-ying~1,JIN Bao-kang~1,SUN Xin~2 |
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| Abstract: | This paper has prepared the NOM/PPD electrode with 1,2-diaza-3,4:9,10- dibenzo-5,8-dioxacyclopentadecane-N,N~(')-diacetic acid(NOM) and o-phenylenediamine(O-PD) by the electropolymerization. The electrochemical behavior of the electrode has been studied by the cyclic voltammetry.The electrode has been used to determine the minim Cu in the serum by the anodic stripping volatammetry and the results are satisfactory. |
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| Keywords: | heteromacrocycle poly(o-phenylenediamine) modified electrode copper |
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