| 碱土金属双原子基团振动特性常数间的关系 |
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| 引用本文： | 马衡,雷友惠,马宇,何萌. 碱土金属双原子基团振动特性常数间的关系[J]. 贵州工业大学学报(自然科学版), 1991, 0(2) |
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| 作者姓名： | 马衡 雷友惠 马宇 何萌 |
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| 作者单位： | 云南大学实验中心，贵州工学院化工系，云南电力设计院，云南301地质队 |
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| 摘 要： | 基团(离子及分子)的红外光谱波数变化复杂。寻找其变化规律性并从基团的物理化学特性上加以阐述,是研究工作的一个重要方面。我们找到了某些碱土金属双原子基团谐振动波数及非谐性常数的规律性变化。由谐振动波数计算得力常数,发现力常数具有规律变化(少数例外)。力常数变化、谐振波数变化及非谐性常数变化基本上具有正相关性。
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| 关 键 词： | 振动力常数 非谐性常数 谐振动波数 红外光谱 拉曼光谱 |
The Relation Between The Vibration Force Constants And Vibration Wave Numbers Or Anharmonicity Constants Of The Alkali Earth Metal Diatomic Groups |
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| Ma Heng. The Relation Between The Vibration Force Constants And Vibration Wave Numbers Or Anharmonicity Constants Of The Alkali Earth Metal Diatomic Groups[J]. Journal of Guizhou University of Technology(Natural Science Edition), 1991, 0(2) |
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| Authors: | Ma Heng |
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| Affiliation: | Ma Heng(Experimental Center of Yunnan University) Lei Youhui(Department of Chemical Engineering) Ma Yu(Yunnan Designing Institute of Electric Power) He Meng(Yunnan 301 Team of Geological Survey) |
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| Abstract: | The vibration force constants were calculated and the regular change of them were found. The changes of vibration force constants, and of harmonicity vibration wave numbers or anharmonicity constants of the Alkali Earth Metal diatomic groups are positively interrelated. |
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| Keywords: | vibration force constant anharmonicity constant vibration wave number infra-red spectrum Raman Spectrum |
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