| 用气相色谱研究[Co(NH_3)_4CO_3]Cl与NH_4SCN取代反应中配合物的结构变化 |
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| 引用本文： | 庄稼,迟燕华. 用气相色谱研究[Co(NH_3)_4CO_3]Cl与NH_4SCN取代反应中配合物的结构变化[J]. 西南科技大学学报, 1992, 0(4) |
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| 作者姓名： | 庄稼 迟燕华 |
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| 作者单位： | 四川建材学院硅酸盐工程系(庄稼)，四川建材学院硅酸盐工程系(迟燕华) |
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| 摘 要： | 根据热分解的气相色谱分析结果推证反应过程的物质结构变化还未见报导.本文采用气查色谱与自制的热分解署联用,对[Co(NH_3)_4CO_3]Cl与NH_4SCN的固相热分解反应过程的产物进行检测。得出该取代反应是按S_N2机理进行的,推证了[CO(NH_3)_4CO_3]Cl和[CO(NH_3)_4CO_3]Cl+NH_4SCN在热分解过程中空间结构的变化。
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| 关 键 词： | 气相色谱 取代反应 [Co(NH_3)_4CO_3]Cl |
Study on Structure Changed of Substitution Reaction of [Co(NH_3)_4CO_3]Cl and NH_4SCN |
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| Zhuang Jia Chi Yanhua. Study on Structure Changed of Substitution Reaction of [Co(NH_3)_4CO_3]Cl and NH_4SCN[J]. Journal of Southwest University of Science and Technology, 1992, 0(4) |
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| Authors: | Zhuang Jia Chi Yanhua |
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| Affiliation: | Sichuan Institute of Building Materials |
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| Abstract: | The reaction production were determined by gas chromatcrgraph in the reaction of thermodecompose between [Co(NH3)4CO3]Cl with NH4SCN. The reaction was believed to proceed trough SN2 mechanism,infcred on tc structure chaanged for [Co(NH3)4CO3]Cl and [Co(NH3)4CO>3]Cl + NH4SCN at thermodecompose. |
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| Keywords: | gas chromatorgaph substitution reaction [Co(NH3)4CO3]Cl |
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