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亚硫酸化混合油脂新工艺的研究
引用本文:宋伟,卢义和,宫素芝. 亚硫酸化混合油脂新工艺的研究[J]. 河北科技大学学报, 2003, 24(2): 23-26
作者姓名:宋伟  卢义和  宫素芝
作者单位:河北科技大学化学与制药工程学院,河北,石家庄,050018
基金项目:河北省科技厅攻关项目(992430150D)
摘    要:主要介绍了制备皮革加脂剂的过程。所做实验是以混合植物油为原料,经氧化、亚硫酸化反应制备皮革加脂剂的新工艺,使用油脂包括质量配比为30%~31%的动物油,其碘值在110~200之间。测定了氧化后油脂的碘值,以及反应后乳液的粒径,找出适宜的氧化温度为110℃,氧化时间为8 h,亚硫酸化时间为6 h,适宜的催化剂用量为原料的1.5%。将油样溶为10%的水溶液,乳化很好,在室温下,24 h内乳液保持稳定,经实验证明,这种产品浸透的皮革柔软、光亮、丰满,具有良好的加脂性能。

关 键 词:加脂剂  氧化  亚硫酸化
文章编号:1008-1542(2003)02-0023-04
修稿时间:2002-10-05

Study on Fat-liquoring Agent of Oxysulfiting Vegetable Oil
SONG Wei,LU Yi-he,GONG Su-zhi. Study on Fat-liquoring Agent of Oxysulfiting Vegetable Oil[J]. Journal of Hebei University of Science and Technology, 2003, 24(2): 23-26
Authors:SONG Wei  LU Yi-he  GONG Su-zhi
Abstract:The article relates a process for the preparation of a fatliquoring agent based on ocysulfited oils of animal and vegetable origin. The oxysulfited reaction adopts material with a 30% to 31% animal oil strength by weight compositions, the fatty substances having iodine numbers of from 110 to 200; and determines iodine value and particle size . The suitable oxidization temprature is 110℃ ,the oxidization time is 8 h and sulfination time is 6 h. Sensible quantity of catalyst is 1. 5% of producer stock. The oxysulfited sample.preferably 10% by weight in water, shows a fine emulsion is formed which is stable over a period of at least one day at room temperature. The products penetrate leather well and impart a soft .light, but full feel. This agent has good f atliquoring properties.
Keywords:fatliquoring agent  oxidization  sulfiting  
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