| 几种桥环化合物Retro-Diels-Aleder反应的活化熵及A因子估算 |
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| 引用本文： | 居冠之,边文生. 几种桥环化合物Retro-Diels-Aleder反应的活化熵及A因子估算[J]. 山东大学学报(理学版), 1991, 0(3) |
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| 作者姓名： | 居冠之 边文生 |
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| 作者单位： | 山东大学理论化学研究室，山东大学理论化学研究室 |
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| 摘 要： | 用简化的过渡态理论(STST),按协同机制,对几种桥环化合物裂解反应的活化熵、A因子作了首次估算.并和实验结果作比较讨论了反应可能进行的机理:解释了反应的A因子递变现象.
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| 关 键 词： | Dicls-A1cder递反应 活化熵 A因子 桥环化合物 反应动力学 反应机理 |
CALCULATION ON THE ACTIVATION ENTROPIES AND A FACTORS OF THE RETRO-DIELS-ALDER REACTIONS FOR SOME BRIDGEDRING COMPOUNDS |
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| Ju Guanzhi,Bian Wensheng. CALCULATION ON THE ACTIVATION ENTROPIES AND A FACTORS OF THE RETRO-DIELS-ALDER REACTIONS FOR SOME BRIDGEDRING COMPOUNDS[J]. Journal of Shandong University, 1991, 0(3) |
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| Authors: | Ju Guanzhi Bian Wensheng |
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| Affiliation: | Ju Guanzhi,Bian Wensheng,Institute of Theoretical Chemistry,Shandong University,Jinan |
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| Abstract: | Using the Simplified Transition State Theory (STST), the activation entropies and A factors of the title reactions have been first calculated according to the con-certed mechanism. The calculated results have been compared with those of experime ntsand the probable mechanisms of the title reactions have been discussed. At the same time, the gradual variety of A factors for the title reactions has also been ex-plained. |
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| Keywords: | Retro-Diels-Aleder reaction activation entroplg A factor bridged-ring compound reaction mechanism reaction kincties |
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