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| 五元杂环取代的茂金属配合物的合成及表征 | |
| 引用本文： | 马志宏,刘晓焕,李素贞,郑学忠,林进. 五元杂环取代的茂金属配合物的合成及表征[J]. 河北师范大学学报(自然科学版), 2012, 36(3): 286-290 |
| 作者姓名： | 马志宏 刘晓焕 李素贞 郑学忠 林进 |
| 作者单位： | 1. 河北师范大学 化学与材料科学学院,河北 石家庄 050024;河北医科大学 基础医学院,河北 石家庄 050017 2. 河北师范大学 化学与材料科学学院,河北 石家庄,050024 3. 河北工业职业技术学院 现代教育技术中心,河北 石家庄,050091 |
| 基金项目： | 河北省自然科学基金(B2008000150);河北师范大学重点基金(L2009Z06);河北省教育厅科研项目(Z2009131) |
| 摘 要： | 将(C5Me4H) C4H3S,(C4H3S)C(CH3)(C2H5)(C5H5)和2- CH3C4H2O(C5Me4H)分别与Mo(CO)6,Ru3(CO)12和Fe(CO)5在二甲苯中加热回流,合成了3个新型的双核配合物[(η5-C5Me4C4H3S) Mo(CO)3]2,[(η5- C5H4)C(CH3) (C2H5) (C4H3S)Ru(CO)2]2和[(η5- C5 Me4(2 - CH3CH2O))Fe(CO)(μ-CO)]2.通过元素分析、红外光谱、核磁共振氧谱对其结构进行了表征. |
| 关 键 词： | 五元杂环 二聚物 环戊二烯基 羰基 |
Synthesis and Characterization of Five-membered Heterocyclic Substitued Metallocene Analogic Complexes |
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| MA Zhihong , LIU Xiaohuan , LI Suzhen , ZHENG Xuezhong , LIN Jin. Synthesis and Characterization of Five-membered Heterocyclic Substitued Metallocene Analogic Complexes[J]. Journal of Hebei Normal University, 2012, 36(3): 286-290 | |
| Authors: | MA Zhihong LIU Xiaohuan LI Suzhen ZHENG Xuezhong LIN Jin |
| Affiliation: | 1(1.College of Chemistry and Material Science,Hebei Normal University,Hebei Shijiazhuang 050024,China;2.College of Basic Medicine,Hebei Medical University,Hebei Shijiazhuang 050017,China;3.Modern Education Technology Center,Hebei College of Industry and Technology,Hebei Shijiazhuang 050091,China) |
| Abstract: | Three new dinuclear complexes,namely [(η5-C5Me4C4H3S)Mo(CO)3]2,[(η5-C5H4)C(CH3)(C2H5)(C4H3S)Ru(CO)2]2 and [(η5-C5Me4(2-CH3C4H2O))Fe(CO)(μ-CO)]2,have been synthesized by the reactions of(C5Me4H)C4H3S,(C4H3S)C(CH3)(C2H5)(C5H5) and 2-CH3C4H2O(C5Me4H),respectively,with Mo(CO)6,Ru3(CO)12 and Fe(CO)5 in refluxing xylene.The three complexes have been characterized by elemental analysis,IR and 1HNMR spectra. |
| Keywords: | five-membered heterocyclic dimer cyclopentadienyl carbonyl |
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