| 钯催化烯丙基酯亲核取代反应的研究进展 |
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| 引用本文： | 钯催化烯丙基酯亲核取代反应的研究进展[J]. 华南师范大学学报（自然科学版）, 2018, 50(5): 45-51. DOI: 10.6054/j.jscnun.2018071 |
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| 作者单位： | 1.(KeyLaboratoryofTheoreticalChemistryofEnvironment,MinistryofEducation∥ |
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| 基金项目： | 国家自然科学基金项目(21172081, 21372090);广东省自然科学基金重点项目(S2013020013091);广州市科技计划项目(201510010054) |
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| 摘 要： | 钯催化不对称烯丙基取代反应是一种合成手性化合物的重要方法之一. 本文综述了近年来钯催化烯丙基酯衍生物亲核取代反应的研究进展，重点讨论了钯催化剂、烯丙基酯衍生物底物的结构、亲核试剂类型、溶剂及添加剂等因素对烯丙基亲核取代反应的影响. 并对可能的反应机理进行了讨论.
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| 关 键 词： | 钯催化 烯丙基酯 亲核试剂 亲核取代反应 研究进展 |
| 收稿时间： | 2018-03-10 |
Progress in Palladium-Catalyzed Allyl Ester Substitution Reaction |
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| YANG Dingqiao, TAN Yun. Progress in Palladium-Catalyzed Allyl Ester Substitution Reaction[J]. Journal of South China Normal University (Natural Science Edition), 2018, 50(5): 45-51. DOI: 10.6054/j.jscnun.2018071 |
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| Authors: | YANG Dingqiao TAN Yun |
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| Affiliation: | 1.(KeyLaboratoryofTheoreticalChemistryofEnvironment,MinistryofEducation∥;2.SchoolofChemistryandEnvironment,SouthChinaNormalUniversity,Guangzhou510006,China) |
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| Abstract: | Palladium-catalyzed allyl ester substitution reaction is one of the most important methods for the synthesis of chiral compounds. The recent research progress in palladium-catalyzed allyl ester substitution reactions and its derivatives is reviewed with focus on the influences of the palladium catalysts, the substrate structures of allylic ester and its derivatives, the type of nucleophiles, solvents and additives on substitution reaction. Moreover, the possible mechanisms of some parts of substitution reactions are also discussed in this review. |
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| Keywords: | recent research progress |
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