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三元溶剂萃取羧酸的机理探讨
引用本文:蓝铁纯,张先进.三元溶剂萃取羧酸的机理探讨[J].广西大学学报(自然科学版),1997,22(1):79-84.
作者姓名:蓝铁纯  张先进
作者单位:广西大学工业测试实验中心,广西南宁市高新技术产业开发区管理办公室
摘    要:对由叔胺、醇(或酮)和煤油组成的三元溶剂中各组分在萃取羧酸过程中的作用机理进行了探讨,推导出三元溶剂-羧酸两相平衡系统的等温分配关系式和羧酸在两相中的平衡浓度与温度的关系式,并根据三元溶剂-醋酸两相平衡系统实验数据对关系式中有关参数进行了回归.

关 键 词:三元溶剂  羧酸  萃取机理  平衡关系式

A Study on the Mechanism of the Extraction of Carboxylic Acids with Three Components Solvent Mixture
Lan Tiechun,Zhang Xianjin,Zhou Yonghong,Xiong Deyuan.A Study on the Mechanism of the Extraction of Carboxylic Acids with Three Components Solvent Mixture[J].Journal of Guangxi University(Natural Science Edition),1997,22(1):79-84.
Authors:Lan Tiechun  Zhang Xianjin  Zhou Yonghong  Xiong Deyuan
Institution:Lan Tiechun 1) Zhang Xianjin 2) Zhou Yonghong 1) Xiong Deyuan 1)
Abstract:The effect of each component of mixed solvents consisting of tertiary amine,alcohol or ketone and kerosene on the extraction of carboxylic acids from water solution is discussed. The isothermal extraction equilibrium equation and the relationship between the temperature and the equilibrium concentrations of carboxylic acid in the organic phase and that in the aqueous phase are inferred. The data of the liquid -liquid equilibrium is related.
Keywords:ternary solvents  carboxylic acids  extrating mechanism  equilibrium equation
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