| 笼状三氟甲基磺酸及磷酸银盐化合物的合成及结构表征 |
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| 引用本文： | 宋鑫波,韩俊萍,郭建平.笼状三氟甲基磺酸及磷酸银盐化合物的合成及结构表征[J].山西大学学报(自然科学版),2011(Z2):52-54. |
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| 作者姓名： | 宋鑫波 韩俊萍 郭建平 |
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| 作者单位： | 山西大学应用化学研究所;固废资源化利用与节能建材国家重点实验室; |
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| 基金项目： | 国家自然科学基金(20872084) |
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| 摘 要： | 以HN(SiMe3)2和LiBun反应制得LiN(SiMe3)2,随后与3-吡啶腈反应,其次再与Ph2PCl反应,最后用氧化剂AgSO3CF3氧化,所得物溶解在乙腈中缓慢挥发溶剂,得到化合物1,Ph12Ag4P6O6(F3CSO3)2的白色晶体,用X-射线单晶衍射仪测定其晶体结构,并用IR对该化合物的官能团进行了分析和表征.
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| 关 键 词： | 金属配合物合成 笼状结构化合物 晶体结构 |
Synthesis and Characterization of Caged Silver Triflate Phosphate |
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| SONG Xin-bo,HAN Jun-ping,GUO Jian-ping.Synthesis and Characterization of Caged Silver Triflate Phosphate[J].Journal of Shanxi University (Natural Science Edition),2011(Z2):52-54. |
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| Authors: | SONG Xin-bo HAN Jun-ping GUO Jian-ping |
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| Institution: | SONG Xin-bo1,HAN Jun-ping1,2,GUO Jian-ping1,2(1.Institute of Applied Chemistry,Shanxi University,Taiyuan 030006,China,2.State Key Laboratory of Solid Waste Reuse for Building Materials,Beijing 100041,China) |
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| Abstract: | Lithiation of HN(SiMe3)2 with LiBun yielded LiN(SiMe3)2.The lithium salt reacted with 3-Cyanopyridine and followed by addition of one equivalent of chlorodiphenylphosphine,then AgSO3CF3 was added to give the compound Ph12Ag4P6O6(F3CSO3)2.The colorless crystalline product was obtained by evaporating the acetonitrile solution in air.The molecular structure was determined by IR and X-ray crystallography. |
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| Keywords: | metal compound caged silver triflate phosphate crystal structure |
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