| 高位阻硅基取代2-氨基吡啶二聚锂化物的合成及表征 |
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| 引用本文： | 余强,马素芳,刘滇生.高位阻硅基取代2-氨基吡啶二聚锂化物的合成及表征[J].山西大学学报(自然科学版),2011(Z2):49-51. |
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| 作者姓名： | 余强 马素芳 刘滇生 |
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| 作者单位： | 山西大学应用化学研究所; |
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| 基金项目： | 国家自然科学基金(20672070;20772074); 山西省自然科学基金(20070110) |
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| 摘 要： | 以2-氨基吡啶为原料,经正丁基锂去氢后与N,N-二(三甲基硅基)]氨基-二甲基氯硅烷反应,再次与正丁基锂反应,合成了一种新型有机锂化合物,并通过X-ray单晶衍射、1 HNMR对该化合物进行了分析和表征.
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| 关 键 词： | 金属锂化物 有机合成 化合物表征 |
Synthesis and Characterization of Dimeric Lithium Complex Based on Bulky Silyl substituted 2-Aminopyridine |
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| YU Qiang,MA Su-fang,LIU Dian-sheng.Synthesis and Characterization of Dimeric Lithium Complex Based on Bulky Silyl substituted 2-Aminopyridine[J].Journal of Shanxi University (Natural Science Edition),2011(Z2):49-51. |
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| Authors: | YU Qiang MA Su-fang LIU Dian-sheng |
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| Institution: | YU Qiang,MA Su-fang,LIU Dian-sheng(Institute of Applied Chemistry,Shanxi University,Taiyuan 030006,China) |
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| Abstract: | The title compound,(Li(((Me3Si)2N)Me2SiNPy)THF)2 was prepared by the reaction of 2-aminopyridine with n-BuLi,and was added(Me3Si)2NMe2SiCl,and then the mixture was fitered,and the filtrate reacted with n-BuLi.The structure of the title compound was characterized by 1H NMR and X-ray analysis. |
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| Keywords: | organolithium complex organic synthesis characterization of complex |
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