| 全氟丁基取代醇,酮和烯烃的制备 |
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| 引用本文： | 荣国斌.全氟丁基取代醇,酮和烯烃的制备[J].华东理工大学学报(自然科学版),1996,22(3):356-361. |
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| 作者姓名： | 荣国斌 |
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| 作者单位： | 华东理工大学化学系 |
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| 摘 要： | 全氟丁基锂与醛，酮，酰氯和酯反应全氟丁基取代醇和酮。在超声作用下，全氟丁工碘与镁作用后也可与醛或酮反应。从全氟丁基取代叔醇的脱水和全氟丁基取代中醇的乙酸酯热解后得到全氟丁基取代烯烃。
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| 关 键 词： | 全氟丁基化 醇 酮 合成 烯烃 |
Preparation of Perfluorobutyl Substituted Alcohols,Ketones and Alkenes |
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| Rong Guobin.Preparation of Perfluorobutyl Substituted Alcohols,Ketones and Alkenes[J].Journal of East China University of Science and Technology,1996,22(3):356-361. |
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| Authors: | Rong Guobin |
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| Abstract: | A series of perfluorobutyl substituted alcohols and ketones were prepared by nucleophilic addition of carbonyl compounds by C_4F_9I with C_4H_9 Li or with Mg under ultrasonic irradiation.The perfluorobutylated olefins were produced via dehydration of the perfluorobutylated tertiary alcohols and by flash pyrolysis of the acetates of the corresponding perfluorobutyled secondary or tertiary alcohols. |
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| Keywords: | perfluorobutylated alcohols ketones olefins synthesis |
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