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Regulatory steps in sex pheromone biosynthesis inMamestra brassicae L. (Lepidoptera: Noctuidae)
Authors:H J Bestmann  M Herrig  A B Attygalle  M Hupe
Institution:(1) Institut für Organische Chemie der Universität Erlangen-Nürnberg, Henkestr. 42, D-8520 Erlangen, Federal Republic of Germany
Abstract:Summary The de novo biosynthesis of (Z)-11-hexadecenyl acetate, the most abundant pheromone component inM. brassicae, starting from acetate via palmitic acid, requires the presence of a pheromone-biosynthesis-activating neurohormone. Moreover, the conversion of palmitic acid to (Z)-11-hexadecenyl acetate is strongly dependent on the presence of the neurohormone. However, no significant dependence was found for the conversion of (Z)-11-hexadecenoic acid to (Z)-11-hexadecenyl acetate. This indicates that the neurohormonal control of pheromone biosynthesis inM. brassicae occurs at the level of palmitic acid.
Keywords:Pheromone biosynthesis regulation  deuterium labeling  brain factor  neurohormone  (Z)-11-hexadecenyl acetate  Mamestra brassicae
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