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用壳聚糖脱除废水中的铜离子
引用本文:张廷安,豆志河.用壳聚糖脱除废水中的铜离子[J].东北大学学报(自然科学版),2006,27(2):203-205.
作者姓名:张廷安  豆志河
作者单位:东北大学,材料与冶金学院,辽宁,沈阳,110004
基金项目:国家自然科学基金资助项目(50174018)
摘    要:研究了利用脱乙酰基壳聚糖絮凝剂絮凝除铜的方法.考察了氢氧化物、pH值、铜离子质量浓度、絮凝时间以及絮凝温度对去除率的影响.当pH=8时,用壳聚糖吸附铜离子,水样铜离子质量浓度低于100 mg.L-1时,除铜率在99%以上;即使铜离子原始质量浓度在400 mg.L-1,残液铜离子质量浓度仍符合国家废水排放标准.用NaOH絮凝沉淀,pH=11时,除铜率达100%,耗碱量大,不符合废水排放的酸度要求.

关 键 词:  废水处理  壳聚糖  絮凝剂  去除率  
文章编号:1005-3026(2006)02-0203-03
收稿时间:2005-06-14
修稿时间:2005年6月14日

Removal of Cu2+ in Wastewater with Chitosan
ZHANG Ting-an,DOU Zhi-he.Removal of Cu2+ in Wastewater with Chitosan[J].Journal of Northeastern University(Natural Science),2006,27(2):203-205.
Authors:ZHANG Ting-an  DOU Zhi-he
Institution:(1) School of Materials and Metallurgy, Northeastern University, Shenyang 110004, China
Abstract:To remove Cu from wastewater using chitosan as flocculants, the effects of hydroxides, pH value, mass concentration of Cu2+ and flocculating time/temperature on removal rate were investigated. When pH value is 8 and the mass concentration of Cu2+ in water is lower than 100 mg·L-1, the removal rate of Cu2+ is higher than 99%. Even the original mass concentration is 400 mg·L-1, the residual mass concentration of Cu2+ is still up to China's national wastewater drainage standard. When using NaOH as flocculant the pH value is 11 and the removal rate of Cu2+ reaches 100%, but the consumption of alkali is too much and the acidity cannot meet the required standard for wastewater drainage.
Keywords:copper  wastewater treatment  chitosan  flocculent  removal rate
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