| 杂多酸掺杂聚苯胺导电复合膜的制备和导电性研究 |
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| 引用本文： | 吕仁江,杨万丽,于海霞,殷广明.杂多酸掺杂聚苯胺导电复合膜的制备和导电性研究[J].高师理科学刊,2011,31(3):62-65. |
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| 作者姓名： | 吕仁江 杨万丽 于海霞 殷广明 |
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| 作者单位： | 齐齐哈尔大学,化学与化学工程学院,黑龙江,齐齐哈尔,161006 |
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| 基金项目： | 黑龙江省教育厅科学技术研究项目 |
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| 摘 要： | 以苯胺作为导电聚合物单体,以醋酸纤维素作为成膜材料,以杂多酸(磷钼酸)为掺杂剂制备了杂多酸/导电聚合物复合膜,采用红外和紫外光谱等测试手段对复合膜进行表征.探索了杂多酸/聚苯胺复合膜制备的最佳工艺条件,并对其导电性能进行了研究.复合膜制备的最佳工艺条件为:苯胺与醋酸纤维素的最佳浓度配比为1:5,反应的最佳温度为15～2...
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| 关 键 词： | 苯胺 杂多酸 导电聚合物 复合膜 导电性 |
Synthesis of heteropoly acid doped polyaniline conductive polymer composite films and conductivity property |
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| LU Ren-jiang,YANG Wan-li,YU Hai-xia,YIN Guang-ming.Synthesis of heteropoly acid doped polyaniline conductive polymer composite films and conductivity property[J].Journal of Science of Teachers＇College and University,2011,31(3):62-65. |
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| Authors: | LU Ren-jiang YANG Wan-li YU Hai-xia YIN Guang-ming |
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| Institution: | (School Chemistry and Chemical Engineering,Qiqihar University,Qiqihar 161006,China) |
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| Abstract: | Aniline as a monomer of conducting polymer,ordinary polymers such as cellulose acetate as film materials and phosphomolybdic acid as dopant,the polyaniline/cellulose acetate conductive polymer composite membranes were prepared.The composition and structure of the composite membrane were tested by IR and UV means.The optimum conditions of preparation of polyaniline/cellulose acetate composite films were also explored,and the conductivity of composite membranes were studied.The optimum conditions preparation of composite membrane,the concentration ratio of aniline and cellulose acetate is 1∶5,the temperature 15~20℃,the reaction time 5 min,and the optimum concentration of oxidant 0.5 mol.L-1.Under such conditions,the electrical conductivity of composite membranes are best. |
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| Keywords: | aniline heteropoly acid conductive polymer composite film conductivity |
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