| MAaBn-a型混配配合物分布系数的极值问题 |
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| 引用本文： | 李可群.MAaBn-a型混配配合物分布系数的极值问题[J].高师理科学刊,2011,31(3):70-72. |
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| 作者姓名： | 李可群 |
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| 作者单位： | 同济大学,化学系,上海,200092 |
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| 摘 要： | 给出了混配配离子MAABB分布系数取最大值的必要条件:nA=a和nB=b(其中:nA和nB分别为混配配合物体系对配体A和配体B的平均配位数);对具有饱和配位数,即MAABn-a型混配配合物分布系数的极值问题进行了探讨.
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| 关 键 词： | 混配配合物 分布系数 极值 平均配位数 |
Extreme values of distribution coefficients of MAaBn-a type mixed ligand coordination compounds |
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| LI Ke-qun.Extreme values of distribution coefficients of MAaBn-a type mixed ligand coordination compounds[J].Journal of Science of Teachers＇College and University,2011,31(3):70-72. |
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| Authors: | LI Ke-qun |
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| Institution: | LI Ke-qun(Department of Chemistry,Tongji University,Shanghai 200092,China) |
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| Abstract: | The necessary conditions of maximum distribution coefficients of mixed ligand coordination compounds were deduced as nA = a and nB = b,where nA and nB are average coordination numbers of mixed ligand coordination compounds to ligand A and ligand B respectively.The extreme values of MAaB n-a type mixed ligand coordination compounds were also discussed theoretically. |
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| Keywords: | mixed ligand coordination compound distribution coefficient extreme value average coordination number |
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