| 连苯三酚型杯芳烃及其酯类衍生物的合成 |
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| 引用本文： | 吴萍,程爱民,汪浩,颜朝国. 连苯三酚型杯芳烃及其酯类衍生物的合成[J]. 安徽大学学报(自然科学版), 2005, 29(6): 70-74 |
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| 作者姓名： | 吴萍 程爱民 汪浩 颜朝国 |
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| 作者单位： | 扬州职业大学,轻纺工程系,江苏,扬州,225009;扬州大学,化学化工学院,江苏,扬州,225002 |
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| 基金项目： | 江苏省自然科学研究指导性计划基金资助项目（04KJD150237） |
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| 摘 要： | 通过连苯三酚和芳香醛在酸性条件下的缩合反应,制备5个连苯三酚型杯芳烃母体;利用溴乙酸乙酯在K2CO3/丙酮体系中对连苯三酚杯芳烃的酚羟基烃基化,得到全衍生物;在乙酸酐中回流得到相应的全乙酰氧基衍生物.化合物结构都用1H NMR和IR表征.
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| 关 键 词： | 连苯三酚型杯芳烃 烃基化 酯类衍生物 |
| 文章编号： | 1000-2162（2005）06-0070-05 |
| 收稿时间： | 2005-09-06 |
| 修稿时间： | 2005-09-06 |
Synthesis of pyrogallolarene and their esters derivatives |
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| WU Ping,CHEN Ai-min,WANG Hao,YAN Chao-Guo. Synthesis of pyrogallolarene and their esters derivatives[J]. Journal of Anhui University(Natural Sciences), 2005, 29(6): 70-74 |
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| Authors: | WU Ping CHEN Ai-min WANG Hao YAN Chao-Guo |
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| Abstract: | Five pyrogallolarenes have been synthesized by the acid catalyzed condensation of a series of aldehyde with pyrogallol in 95% ethanol at the temperature of 70℃ to 75℃ over a period of 3 days.Through the alkylation of ethyl bromacetate with these pyrogallolarenes in the condition of K_(2)CO_(3)/acetone and refluxing pyrogallolarenes in Ac_(2)O,two kinds of ester derivatives containing ethoxyl carbonyl methoxyl and acetyl terminal groups,respectively,were easily obtained.All the organic compounds were characterized by IR and ~(1)HNMR spectroscopy. |
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| Keywords: | calixarene pyrogallolarene alkylation ester derivatives |
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