| 偶氮,亚胺,酯类液晶的合成及中心桥键对介晶性的影响研究 |
| |
| 引用本文： | 徐成刚,汪必琴,胡平,赵可清.偶氮,亚胺,酯类液晶的合成及中心桥键对介晶性的影响研究[J].四川师范大学学报(自然科学版),2000,23(6):630-633. |
| |
| 作者姓名： | 徐成刚 汪必琴 胡平 赵可清 |
| |
| 作者单位： | 四川师范大学,化学与生命科学学院,四川,成都,610066 |
| |
| 基金项目： | 四川省教育厅资助项目 |
| |
| 摘 要： | 报道了偶氮化合物ｐ－Ｈ２１Ｃ１０Ｏ－Ｃ６Ｈ４－Ｎ→‖Ｎ－Ｃ６Ｈ４－ＣＯＯＣｈ，亚胺化合物ｐ－Ｈ２１Ｃ１０Ｏ－Ｃ６Ｈ４－ＣＨ→‖Ｎ－Ｃ６Ｈ４－ＣＯＯＣｈ，酯类化合物ｐ－Ｈ２１Ｃ１０Ｏ－Ｃ６Ｈ４－ＣＯＯＣｈ，（Ｃｈ ａｓ ｔｈｅ ａｂｂｒｅｖｉａｔｉｏｎ ｏｆ ｃｈｏｌｅｓｔｅｒｙｌ ｇｒｏｕｐ）的合成，结构鉴定，以及ＤＳＣ和偏光显微镜对其介晶性研究的结果，并对中心桥键对介晶性的影响进行了讨论。
|
| 关 键 词： | 液晶 合成 中心桥键 介晶性 偶氮 亚胺 酯类 |
| 修稿时间： | : |
Synthesis of Diazo, Imine, and Ester Liquid Crystals and the Effect of Central-bridge-bond on the Mesophase Behavior |
| |
| XU Cheng-gang,WANG Bi-qin,HU Ping,ZHAO Ke-qing.Synthesis of Diazo, Imine, and Ester Liquid Crystals and the Effect of Central-bridge-bond on the Mesophase Behavior[J].Journal of Sichuan Normal University(Natural Science),2000,23(6):630-633. |
| |
| Authors: | XU Cheng-gang WANG Bi-qin HU Ping ZHAO Ke-qing |
| |
| Abstract: | Three substituted cholesteryl benzoate compounds, diazo compound p-H21C10O-C6H4-N-N-C6H4-COOCh, the imine compound p-H21C10O-C6H4-CH-N-C6H4-COOCh, the ester compound p-H21C10O-C6H4-COO-C6H4-COOCh, (Ch as the abbreviation of cholesteryl) were synthesized and their structures were characterized through IR and 1H NMR. The liquid crystal properties were investigated through DSC and polarizing microscope. They show cholesteric phase in the temperature range of 268～312, 231～278 and 203～329℃ for diazo, imine and ester respectively. The effect of central-bridge-bond on the mesophase behavior was discussed. |
| |
| Keywords: | Liquid crystal Cholesteric phase Syn thesis |
| 本文献已被 维普 万方数据 等数据库收录！ |
|
