| 甲醇重整制氢反应器的模拟研究 |
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| 引用本文： | 魏昆,纪培军. 甲醇重整制氢反应器的模拟研究[J]. 北京化工大学学报(自然科学版), 2009, 36(4): 17-20 |
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| 作者姓名： | 魏昆 纪培军 |
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| 作者单位： | 北京化工大学,化学工程学院,北京,100029;北京化工大学,化学工程学院,北京,100029 |
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| 摘 要： | 在Peppley等人提出的甲醇水蒸汽重整反应机理的基础上建立了甲醇重整制氢反应器的模型。并依据所建立的模型对不同压力及空速下甲醇的转化率进行了模拟并与实验数据进行了对比，结果显示甲醇转化率的模拟值与实验数据有较好的吻合（相对误差1.13%）。在所建立模型的基础上，进一步地讨论了反应器入口甲醇比率和入口温度对甲醇转化率以及单位甲 醇制氢量的影响。并得出了在所给出的操作条件下，当入口温度为570K，FM,R/FM,B=8.5时，单位甲醇的制氢量最高，可达到2.64（mol/mol）。
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| 关 键 词： | 反应机理 重整模型 甲醇转化率 |
| 收稿时间： | 2008-11-10 |
Simulation of a methanol reforming reactor |
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| WEI Kun,JI PeiJun. Simulation of a methanol reforming reactor[J]. Journal of Beijing University of Chemical Technology, 2009, 36(4): 17-20 |
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| Authors: | WEI Kun JI PeiJun |
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| Affiliation: | College of Chemical Engineering, Beijing University of Chemical Technolo gy, Beijing 100029, China |
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| Abstract: | A model for a methanol reforming reactor has been established based on the mecha nism of the production of hydrogen by methanol steam reforming proposed by Peppley et al. Simulation of the steam reforming of methanol has been carried out, an d the results compared with experimental data obtained under different operating conditions. The relative error between the simulated and experimental results was found to be 1.13%. Under the optimal conditions, with an inlet temperature o f 570K and ratio of flow rate of methanol in the reforming reactor to that in the combustion chamber (FM,R/FM,B) of 8.5, the simulation results showed that the maximum hydrogen production can reach 2.64(mol/mol). |
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| Keywords: | reaction mechanism reforming model methanol conversion |
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