| EPDM磺酸盐离聚体溶液粘度行为的研究 |
| |
| 引用本文： | 冯克,欧阳巍,李卓美.EPDM磺酸盐离聚体溶液粘度行为的研究[J].中山大学学报(自然科学版),1993(1). |
| |
| 作者姓名： | 冯克 欧阳巍 李卓美 |
| |
| 作者单位： | 中山大学高分子研究所
(冯克，欧阳巍)，中山大学高分子研究所(李卓美) |
| |
| 摘 要： | 考察了在二甲苯-正已醇混合溶剂中,含不同金属离子Li~+、Na~+、K~+和Mg~(2+)、Ca~(2+)、Ba~(2+)的六种乙丙三元共聚物(EPDM)磺酸盐离聚体,比浓粘度与溶液浓度、温度及极性共溶剂含量的关系,认为各种金属盐的差异主要是由于溶液中金属离子与SO_3~-之间的相互作用造成的.
|
| 关 键 词： | 离聚体 EPDM磺酸盐 溶液粘度行为 红外光谱 |
Study on Viscometric Behavior of Sulfonated EPDM Ionomer Solution |
| |
| Feng Ke Ouyang Wei Li Zhuomei.Study on Viscometric Behavior of Sulfonated EPDM Ionomer Solution[J].Acta Scientiarum Naturalium Universitatis Sunyatseni,1993(1). |
| |
| Authors: | Feng Ke Ouyang Wei Li Zhuomei |
| |
| Institution: | Feng Ke Ouyang Wei Li Zhuomei |
| |
| Abstract: | The viscometric behavior of sulfonated EPDM ionomers containingLi~+,Na~+,K~+,Mg~(2+),Ca~(2+) and Ba~(2+) has been investigated in a mixed solvent ofxylene and hexanol.The reduced viscosity-concentration and reduced viscosity-temperature relationshipso ionomers are very different from that of EPDM ow-ing to the interaction between ionic groups.The interaction of metallic ions withSO_3~- decreases in the order Ba>Ca>Mg and K>Na>Li.These observa-tions are interpreted as arising from the different hexanol-solvation ability ofthe metallic ions and the temperature-dependent stability of the solvation layeraround them.The obtained results are further conformed with FTIR analysis insame solvent system. |
| |
| Keywords: | ionomer metal sulfonated EPDM viscometric behavior in solution infrared spectra |
| 本文献已被 CNKI 等数据库收录！ |
