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十二烷基苯磺酸钠对抗菌陶瓷釉料分散稳定性的影响
引用本文:柴立元,程明明,彭兵,黄毅,张晓飞. 十二烷基苯磺酸钠对抗菌陶瓷釉料分散稳定性的影响[J]. 中南大学学报(自然科学版), 2006, 37(6): 1107-1111
作者姓名:柴立元  程明明  彭兵  黄毅  张晓飞
作者单位:中南大学,冶金科学与工程学院,湖南,长沙,410083
摘    要:研究抗菌釉料(石灰石、长石、石英、高岭土及抗菌剂-纳米TiO2)对表面活性剂十二烷基苯磺酸钠(SDBS)的吸附性能,利用吸附等温线分析其吸附行为。采用分光光度法在500nm处测定抗菌釉浆的吸光度,并结合釉浆中微粒的Zeta电位,考察釉浆稳定性与pH值、NaCl浓度和表面活性剂浓度之间的关系。结合扫描电镜照片观察釉浆沉积物形貌,并分析SDBS在抗菌釉料中的吸附机理。研究结果表明:影响吸附SDBS釉浆体系Zeta电位的主要因素是pH值;当吸附SDBS的釉浆在pH=7,NaCl浓度为10mmol/L时达到最佳分散稳定效果。

关 键 词:抗菌釉料  表面活性剂  吸附等温线  分散稳定性  Zeta电位
文章编号:1672-7207(2006)06-1107-05
收稿时间:2006-04-26
修稿时间:2006-04-26

Effect of dodecylbenzenesulfonate on dispersion stability of antibacterial ceramic glaze
CHAI Li-yuan,CHENG Ming-ming,PENG Bing,HUANG Yi,ZHANG Xiao-fei. Effect of dodecylbenzenesulfonate on dispersion stability of antibacterial ceramic glaze[J]. Journal of Central South University:Science and Technology, 2006, 37(6): 1107-1111
Authors:CHAI Li-yuan  CHENG Ming-ming  PENG Bing  HUANG Yi  ZHANG Xiao-fei
Affiliation:School of Metallurgical Science and Engineering, Central South University, Changsha 410083, China
Abstract:The adsorption of sodium dodecylbenzenesulfonate(SDBS) onto a antibacterial ceramic glaze mixture composed of nano-TiO_2 limestone,feldspar,quartz,and kaolin was investigated.Both adsorption isotherms and the average particle Zeta potential were studied in order to understand the suspension stability as a function of pH value,NaCl concentration,and surfactant concentration.Microstructure of ceramic glaze was observed by scanning electron microscope,and the mechanisms of surfactant adsorption were investigated.The results show that the dispersion stability of the ceramic glaze is the best in the presence of SDBS at pH 7 in 10 mmol/L NaCl(solution.)
Keywords:antibacterial glaze   surfactant   adsorption isotherms   dispersion stability   Zeta potential
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