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非均相稀土有机金属催化剂研究进展
引用本文:管施恩,徐嘉欣,陈峰,汪臻,陈明真,梁超,张昉.非均相稀土有机金属催化剂研究进展[J].上海师范大学学报(自然科学版),2013,42(6):605-614.
作者姓名:管施恩  徐嘉欣  陈峰  汪臻  陈明真  梁超  张昉
作者单位:上海师范大学生命与环境科学学院,上海200234
基金项目:国家自然科学基金(21107071,51273112)
摘    要:近年来,非均相稀土有机金属催化剂由于其可克服均相稀土有机金属络合物固有的稳定性差以及难以重复使用等缺点,引起了人们的浓厚兴趣和足够重视.着重介绍了非均相稀土三氟磺酸基有机金属催化剂和非均相稀土胺基有机金属催化剂的研究进展及其在精细有机合成中的应用,并对将来稀土有机金属催化剂的设计合成进行了展望.

关 键 词:稀土有机金属  非均相催化剂  固载化
收稿时间:2013/9/23 0:00:00

Research progress inheterogeneous rare earth organometallic catalysts
GUAN Shien,XU jiaxin,CHEN Feng,WANG Zhen,CHEN Mingzhen,LIANG Chao and ZHANG Fang.Research progress inheterogeneous rare earth organometallic catalysts[J].Journal of Shanghai Normal University(Natural Sciences),2013,42(6):605-614.
Authors:GUAN Shien  XU jiaxin  CHEN Feng  WANG Zhen  CHEN Mingzhen  LIANG Chao and ZHANG Fang
Institution:Fang (College of Life and Environment Sciences, Shanghai Normal University, Shanghai 200234, China)
Abstract:The use of heterogeneous rare earth organometallic catalysts for organic synthesis has attracted much attention recently since they possess the enhanced stability and reusability. In this review, we mainly present the latest developments in the design and synthesis of heterogeneous rare earth triflate catalysts and heterogeneous rare earth amide catalysts and their applications in fine organic synthesis. Also,we discuss the outlook for the design and synthesis of rare earth organometallic catalysts.
Keywords:rare earth organometal  heterogeneous catalyst  immobilization
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