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碳掺杂ZnO的制备及光电性能
引用本文:张凌云,吴钊成,贾若琨,杨玉林. 碳掺杂ZnO的制备及光电性能[J]. 东北师大学报(自然科学版), 2012, 0(1): 107-110
作者姓名:张凌云  吴钊成  贾若琨  杨玉林
作者单位:东北电力大学化学工程学院;中国石油吉林石化公司;哈尔滨工业大学化工学院
基金项目:国家自然科学基金资助项目(5100301);吉林省教育厅基金资助项目(2009092)
摘    要:以乙烯基乙二醇为C源,通过简单的液相法制备了C掺杂的ZnO.通过XRD和XPS分析确定C取代ZnO中的O位,掺杂后的ZnO仍为六方纤锌矿结构.将C掺杂ZnO用作染料敏化太阳能电池阳极材料,电池性能各项参数均有所提高,其中光电流提高了40%,光电转化效率提高了32%.采用交流阻抗进一步研究了ZnO染料敏化太阳能电池界面电阻和电子传输性质.

关 键 词:染料敏化  太阳能电池  ZnO    掺杂

Preparation and photoelectricity performance of carbon doped ZnO
ZHANG Ling-yun,WU Zhao-cheng,JIA Ruo-kun,YANG Yu-lin. Preparation and photoelectricity performance of carbon doped ZnO[J]. Journal of Northeast Normal University (Natural Science Edition), 2012, 0(1): 107-110
Authors:ZHANG Ling-yun  WU Zhao-cheng  JIA Ruo-kun  YANG Yu-lin
Affiliation:1.School of Chemical Engineering,Northeast Dianli University,Jilin 132012,China; 2.China Petrochemical Co.Ltd.Jilin Branch,Jilin 132012,China; 3.College of Chemical Technology,Harbin Institute of Technology,Harbin 150001,China.)
Abstract:In this paper,carbon doped ZnO was prepared by simple solution method using ethylene glycol as carbon source.XRD and XPS indicate that C substituted O position in ZnO lattice and the C doped ZnO was still hexagonal wurtzite structure.The performances of C doped ZnO based on dye-sensitized solar cell were improved than un-doped ZnO.The photocurrent was improved 40% and photo electivity conversion efficiency was improved 32%.The Electrochemical impedance spectroscopy was used to study the resistance in the interface of dye-sensitized solar cell and transmission property of the electron.
Keywords:dye-sensitized  solar cell  ZnO  carbon  doping
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