| 研究非平衡等离子由CH4加CO2 偶联制C2烃类反应机理 |
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| 引用本文： | 季金美,姜玄珍.研究非平衡等离子由CH4加CO2 偶联制C2烃类反应机理[J].青海大学学报,2005,23(5):68-69,88. |
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| 作者姓名： | 季金美 姜玄珍 |
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| 作者单位： | [1]青海师范大学化学系,青海西宁810008 [2]浙江大学化学系,浙江杭州310027 |
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| 摘 要： | O2电晕放电条件下能产生O/O^-活性粒子,选用CO2作氧化剂,代替O2来实现CH4的氧化偶联,提出了反应机理,并通过CH4/CO2比值对反应体系（封闭）的影响,证实反应机理的可靠性.
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| 关 键 词： | 非平衡等离子体 氧化偶联 电晕放电 |
| 文章编号： | 1006-8996（2005）05-0068-02 |
| 收稿时间： | 2005-03-19 |
| 修稿时间： | 2005-03-19 |
The mechanism of oxidative coupling of methane to prepare C2 hydroearbon by non-equilibrium plasma in the presence of carbon oxide |
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| JI Jin - mei, JIANG Xuan - zhen.The mechanism of oxidative coupling of methane to prepare C2 hydroearbon by non-equilibrium plasma in the presence of carbon oxide[J].Journal of Qinghai University(Natural Science),2005,23(5):68-69,88. |
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| Authors: | JI Jin - mei JIANG Xuan - zhen |
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| Institution: | 1. Department of Chemistry, Qinghai Normal Univrsity, Xining 810008, China; 2. Department of Chemistry, University of Zhejiang, Hangzhou 310027, China |
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| Abstract: | Oxygen can produce active oxygen free radical and oxygen anion under corona discharge. As the substituent of oxygen, carbon dioxide was employed as oxident to proceed oxidative coupling of methane. The possible mechanism was put forward and its authenticity was approved through checking the effect of molar ratio between methane and carbon dioxide in the closed reaction system. |
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| Keywords: | non equilibrium plasma oxidative coupling corona discharge |
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