| 过渡金属取代的钨铁杂多配合物的合成与性质 |
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| 引用本文： | 余新武.过渡金属取代的钨铁杂多配合物的合成与性质[J].湖北师范学院学报(自然科学版),2000,20(1):1-4. |
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| 作者姓名： | 余新武 |
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| 作者单位： | 湖北师范学院化学系,黄石,435002 |
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| 基金项目： | Supported by The Natural Science Foundation of Hubei Education commission |
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| 摘 要： | 合成了系列由过渡金属取代的三元钨铁杂多配合物K7FeW11O39Z(H2O)·xH2O(Z=Co、Ni、Cu和Zn),其结构由元素分析、红外、紫外、极谱等手段确证,并测定了合成配合物的导电率.结果表明,配合物的vw-od、λob/oc→w、E1/2(1)和导电率随取代原子不同而呈现规律性变化.
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| 关 键 词： | 钨铁杂多配合物 合成 性质 |
SYNTHESIS AND PROPERTIES OF TUNGSTOFERRATE HETEROPOLY COMPLEXES CONTAINING TRANSITION METAL |
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| Abstract.SYNTHESIS AND PROPERTIES OF TUNGSTOFERRATE HETEROPOLY COMPLEXES CONTAINING TRANSITION METAL[J].Journal of Hubei Normal University(Natural Science),2000,20(1):1-4. |
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| Authors: | Abstract |
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| Abstract: | A series of ternary tungstoferrate heteropoly complexes containing transition metal, K7 FeWu O39 Z (H2O)] · XH2O (Z = Co, Ni, Cu, Zn), have been prepared and characterized by elemental analysis, UV, IR and polarogram. The conductivity of the products was determined. The results show that the vw-od, λob/oc→w, E1/2 (1)and conductivity of the products change regularly with the substituted atom Z, which is due to the natural structure of heteropolyanions FeW11Z. |
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| Keywords: | Tungstoferrate Synthesis Properties |
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