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采用FTIR方法研究乙烯三聚制备 1-己烯催化剂的配位方式。结果表明,在该催化剂体系 (异辛酸铬/三乙基铝/烷基吡咯/四氯乙烷)中存在几种不同结构的配位化合物,而这几种配位方式会在聚合过程中起到不同的催化作用。 相似文献
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H^+ concentration induced-monomerization or trimerization of photosystem Ⅰ (PSI) in cyanobacteria has never been directly observed. In this work, taking characteristic spectra for the trimers and monomers as the indicators, it was experimentally demonstrated that H^+ could induce the oligomeric changes of PSI reaction centers in the intact Spirulina platensis cells and also in the isolated thylakoid membrane complexes. Especially, the higher concentration of H^+ would induce the monomerization while the lower the trimerization, suggesting the electrostatic interaction should be mainly responsible for changes in the oligomeric state of PSI in Spirulina platensis. 相似文献
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